FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3004882533> ?p ?o ?g. }

• W3004882533 endingPage "4410" @default.
• W3004882533 startingPage "4400" @default.
• W3004882533 abstract "The elucidation of the requirements for efficient catalysis within supramolecular host systems is an important prerequisite for developing novel supramolecular catalysts. The resorcinarene hexamer has recently been shown to be the first supramolecular catalyst to promote the tail-to-head terpene cyclization in a biomimetic fashion. We herein present the synthesis of a number of resorcinarene-based macrocycles composed of different ratios of resorcinol and pyrogallol units capable of self-assembly and compare the corresponding assemblies regarding their catalytic activity in the cyclization of monoterpenes. The assemblies were investigated in detail with respect to a number of properties including the encapsulation of substrate and ion pairs, the structural incorporation of water, and the response to externally added acid (HCl). The results obtained strongly indicate that water incorporated into the hydrogen-bond network of the self-assembled structure plays an integral role for catalysis, effectively acting as a proton shuttle to activate the encapsulated substrate. These findings are also supported by molecular dynamics simulations, providing further insight into the protonation pathway and the relative energies of the intermediates involved." @default.
• W3004882533 created "2020-02-14" @default.
• W3004882533 creator A5030768426 @default.
• W3004882533 creator A5052177438 @default.
• W3004882533 creator A5055567825 @default.
• W3004882533 creator A5084661514 @default.
• W3004882533 date "2020-02-07" @default.
• W3004882533 modified "2023-10-01" @default.
• W3004882533 title "Requirements for Terpene Cyclizations inside the Supramolecular Resorcinarene Capsule: Bound Water and Its Protonation Determine the Catalytic Activity" @default.
• W3004882533 cites W1485261648 @default.
• W3004882533 cites W1552092570 @default.
• W3004882533 cites W1608969291 @default.
• W3004882533 cites W1836862903 @default.
• W3004882533 cites W1912487092 @default.
• W3004882533 cites W1966870793 @default.
• W3004882533 cites W1967552344 @default.
• W3004882533 cites W1969932195 @default.
• W3004882533 cites W1970151522 @default.
• W3004882533 cites W1972074240 @default.
• W3004882533 cites W1975255044 @default.
• W3004882533 cites W1977780957 @default.
• W3004882533 cites W1978065331 @default.
• W3004882533 cites W1979576382 @default.
• W3004882533 cites W1981032389 @default.
• W3004882533 cites W1981368803 @default.
• W3004882533 cites W1992097701 @default.
• W3004882533 cites W1992665072 @default.
• W3004882533 cites W1995984011 @default.
• W3004882533 cites W1996313795 @default.
• W3004882533 cites W2002844138 @default.
• W3004882533 cites W2004885278 @default.
• W3004882533 cites W2024872256 @default.
• W3004882533 cites W2027583333 @default.
• W3004882533 cites W2032939764 @default.
• W3004882533 cites W2034793276 @default.
• W3004882533 cites W2049738344 @default.
• W3004882533 cites W2055948489 @default.
• W3004882533 cites W2057806291 @default.
• W3004882533 cites W2061996969 @default.
• W3004882533 cites W2065861418 @default.
• W3004882533 cites W2071750044 @default.
• W3004882533 cites W2072714579 @default.
• W3004882533 cites W2077751959 @default.
• W3004882533 cites W2086513155 @default.
• W3004882533 cites W2089799306 @default.
• W3004882533 cites W2092157292 @default.
• W3004882533 cites W2094104884 @default.
• W3004882533 cites W2095523968 @default.
• W3004882533 cites W2096921126 @default.
• W3004882533 cites W2102217614 @default.
• W3004882533 cites W2116958739 @default.
• W3004882533 cites W2124413194 @default.
• W3004882533 cites W2134149462 @default.
• W3004882533 cites W2134696809 @default.
• W3004882533 cites W2135166675 @default.
• W3004882533 cites W2141838908 @default.
• W3004882533 cites W2143745773 @default.
• W3004882533 cites W2149430024 @default.
• W3004882533 cites W2149655632 @default.
• W3004882533 cites W2152572188 @default.
• W3004882533 cites W2160944863 @default.
• W3004882533 cites W2161186825 @default.
• W3004882533 cites W2167468911 @default.
• W3004882533 cites W2169594520 @default.
• W3004882533 cites W2170242620 @default.
• W3004882533 cites W2172090226 @default.
• W3004882533 cites W2177638519 @default.
• W3004882533 cites W2187054373 @default.
• W3004882533 cites W2319151201 @default.
• W3004882533 cites W2325591946 @default.
• W3004882533 cites W2329400755 @default.
• W3004882533 cites W2346197151 @default.
• W3004882533 cites W2493239270 @default.
• W3004882533 cites W2508435391 @default.
• W3004882533 cites W2552532929 @default.
• W3004882533 cites W2606656135 @default.
• W3004882533 cites W2622567059 @default.
• W3004882533 cites W2750432728 @default.
• W3004882533 cites W2883486454 @default.
• W3004882533 cites W2889146655 @default.
• W3004882533 cites W2895662576 @default.
• W3004882533 cites W2896469357 @default.
• W3004882533 cites W2903308012 @default.
• W3004882533 cites W2904442497 @default.
• W3004882533 cites W2905765615 @default.
• W3004882533 cites W2909454831 @default.
• W3004882533 cites W2912106826 @default.
• W3004882533 cites W2915067821 @default.
• W3004882533 cites W2921266197 @default.
• W3004882533 cites W2921932661 @default.
• W3004882533 cites W2941244538 @default.
• W3004882533 cites W2942917660 @default.
• W3004882533 cites W2946697262 @default.
• W3004882533 cites W2949795040 @default.
• W3004882533 cites W2952083697 @default.
• W3004882533 cites W2953222385 @default.
• W3004882533 cites W2954825093 @default.
• W3004882533 cites W2962505941 @default.

• next