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- W3005001202 endingPage "120805" @default.
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- W3005001202 abstract "The present study investigates the analytical potential of low-temperature photoluminescence spectroscopy for the analysis of seven phenanthrothiophenes with molecular mass 234 g mol−1. The studied PASHs include Phenanthro [1,2-b]thiophene, Phenanthro [2,1-b]thiophene, Phenanthro [2,3-b]thiophene, Phenanthro [3,2-b]thiophene, Phenanthro [3,4-b]thiophene, Phenanthro [4,3-b]thiophene and Phenanthro [9,10-b]thiophene. Excitation and emission spectra recorded from n-alkane solutions at room temperature, 77 K and 4.2 K show phosphorescence emission from all the studied isomers at cryogenic temperatures. The analytical figures of merit obtained under steady state (fluorescence) and time-resolved (phosphorescence) conditions provide limits of detection at the parts-per-billion (ng mL−1) concentration levels. Processing 77 K and 4.2 K phosphorescence data with parallel factor analysis showed to be a robust approach to the determination of phenanthro-thiophenes in complex fluorophore mixtures." @default.
- W3005001202 created "2020-02-14" @default.
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- W3005001202 date "2020-05-01" @default.
- W3005001202 modified "2023-09-26" @default.
- W3005001202 title "Low-temperature time-resolved phosphorescence excitation emission matrices for the analysis of phenanthro-thiophenes in chromatographic fractions of complex environmental extracts" @default.
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- W3005001202 doi "https://doi.org/10.1016/j.talanta.2020.120805" @default.
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