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• W3005104156 abstract "The electrochemical properties of two complexes, [Ru II (η 3 ‐(N,N,N)‐ OMe PDI)Cl 2 (PPh 3 )] 0 ( 1 ) and [Ru II (η 2 ‐(C,N)‐ OMe PDI‐H)Cl (PPh 3 ) 2 ] 0 ( 2 ), were studied. In octahedral complex 1 , bis(imino)pyridine (PDI) is a tridentate η 3 ‐N,N,N‐coordinated ligand, whereas in trigonal‐bipyramidal complex 2 , the deprotonated PDI ligand adopts the unusual bidentate binding mode η 2 ‐C,N to coordinate to the central Ru(II) ion. Bulk electrolysis in two electrolyte solutions of acetonitrile (MeCN) and tetrahydrofuran (THF) suggests that complexes 1 and 2 have very different electrocatalytic CO 2 reduction activities. In MeCN solution, complex 1 can selectively electrocatalytic CO 2 reduction to CO with a Faradaic efficiency of about 50% and a turnover frequency (TOF) of 4.4 s −1 , whereas complex 2 can perform electrocatalytic of CO 2 reduction with a Faraday efficiency of ~22% and a TOF of 0.3 S −1 . The electrocatalytic CO 2 reduction selectivity and activity of the two complexes are poor when the solvent is changed to THF. Combined with the results of the density functional theory calculation, we propose that the binding pattern of the redox‐active ligand OMe PDI has a significant effect on the electrocatalytic activity for the two Ru(II)PDI complexes." @default.
• W3005104156 created "2020-02-14" @default.
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• W3005104156 date "2020-02-09" @default.
• W3005104156 modified "2023-09-25" @default.
• W3005104156 title "Effect of PDI ligand binding pattern on the electrocatalytic activity of two Ru(II) complexes for CO ₂ reduction" @default.
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• W3005104156 doi "https://doi.org/10.1002/aoc.5551" @default.
• W3005104156 hasPublicationYear "2020" @default.
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