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- W3005655582 abstract "Late transition metal palladium catalysts chelated by benchmark α-diimine, phosphine-sulfonate, bisphosphine-monoxide ligands are of great interest for ethylene polymerization and challenging copolymerization with polar comonomers. Compared to numerous studies on the classic α-diimine and phosphine-sulfonate palladium catalysts, the new generation bisphosphine-monoxide palladium (BPMO-Pd) system is far less investigated. In this contribution, by skillfully designing a family of BPMO-Pd catalysts bearing differed steric and electronic P(III) phosphine groups, differed steric and electronic O = P(V) phosphine monoxide groups, and different connectivity of them, a comprehensive picture on catalyst structure construction is built for ethylene (co)polymerizations. This constructed catalyst structure-polymerization property relationship paves the way for the development of more efficient late transition metal catalysts for olefin (co)polymerization." @default.
- W3005655582 created "2020-02-24" @default.
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- W3005655582 date "2020-03-01" @default.
- W3005655582 modified "2023-09-24" @default.
- W3005655582 title "A comprehensive picture on catalyst structure construction in palladium catalyzed ethylene (co)polymerizations" @default.
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- W3005655582 doi "https://doi.org/10.1016/j.jcat.2020.01.032" @default.
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