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• W3005736856 startingPage "3285" @default.
• W3005736856 abstract "A series of Pd-ZnO/TiO2, Pd/TiO2, and Pd/ZnO catalysts were synthesized and investigated for N-methylation of N-methylaniline (MA) to N,N-dimethylaniline (DMA) with CO2 and H2. A high performance was observed with a Pd-ZnO/TiO2 catalyst, with 99.9% DMA selectivity at 94% MA conversion. By contrast, both Pd/TiO2 and Pd/ZnO were less active and/or selective. The catalytic performance of Pd-ZnO/TiO2 largely depended on reduction temperature and ZnO loading. The rates for MA conversion (rateMA) and DMA production (rateDMA) increased linearly with the amount of PdZn alloy formed. The reaction was likely to take place via intermediates of N-methylformanilide (MFA) and formate. Formate was produced through the reduction of CO2 with H2 as confirmed by in situ diffuse reflectance Fourier transform infrared spectroscopy and then added to MA producing MFA, and finally, MFA was subsequently adsorbed and hydrogenated to DMA. All these steps were promoted by the PdZn alloy. The hydrogenation of MFA to DMA was much faster than the N-methylation of MA to MFA; DMA was stable, so the selectivity to DMA was almost 100% over the Pd-ZnO/TiO2 catalyst." @default.
• W3005736856 created "2020-02-24" @default.
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• W3005736856 date "2020-02-11" @default.
• W3005736856 modified "2023-10-13" @default.
• W3005736856 title "Selective N-Methylation of <i>N</i>-Methylaniline with CO₂ and H₂ over TiO₂-Supported PdZn Catalyst" @default.
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• W3005736856 doi "https://doi.org/10.1021/acscatal.9b04677" @default.
• W3005736856 hasPublicationYear "2020" @default.
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