Matches in SemOpenAlex for { <https://semopenalex.org/work/W3005803670> ?p ?o ?g. }
- W3005803670 endingPage "2037" @default.
- W3005803670 startingPage "2032" @default.
- W3005803670 abstract "We report the enantioselective formation of quaternary stereogenic centers by the intermolecular addition of malononitrile, an acyl anion equivalent, and related pronucleophiles to several 1,3-disubstituted acyclic 1,3-dienes in the presence of a Pd-PHOX catalyst. Products are obtained in up to 88% yield and 99:1 er and in most cases are formed as a single regioisomer. The products' malononitrile unit undergoes oxidative functionalization to afford β,γ-unsaturated carbonyls bearing internal olefins and α-quaternary stereogenic centers." @default.
- W3005803670 created "2020-02-24" @default.
- W3005803670 creator A5034500497 @default.
- W3005803670 creator A5037934054 @default.
- W3005803670 creator A5056836858 @default.
- W3005803670 creator A5065064293 @default.
- W3005803670 creator A5072135340 @default.
- W3005803670 date "2020-02-13" @default.
- W3005803670 modified "2023-10-02" @default.
- W3005803670 title "Enantioselective Construction of Quaternary Stereogenic Centers by the Addition of an Acyl Anion Equivalent to 1,3-Dienes" @default.
- W3005803670 cites W1971874689 @default.
- W3005803670 cites W1982832174 @default.
- W3005803670 cites W2002759997 @default.
- W3005803670 cites W2009381692 @default.
- W3005803670 cites W2018729897 @default.
- W3005803670 cites W2033512764 @default.
- W3005803670 cites W2038360178 @default.
- W3005803670 cites W2049103820 @default.
- W3005803670 cites W2072591300 @default.
- W3005803670 cites W2075259140 @default.
- W3005803670 cites W2122994431 @default.
- W3005803670 cites W2149452392 @default.
- W3005803670 cites W2318461157 @default.
- W3005803670 cites W2318894119 @default.
- W3005803670 cites W2341320480 @default.
- W3005803670 cites W2413961131 @default.
- W3005803670 cites W2442050547 @default.
- W3005803670 cites W2462789330 @default.
- W3005803670 cites W2537331024 @default.
- W3005803670 cites W2566479290 @default.
- W3005803670 cites W2572069925 @default.
- W3005803670 cites W2574776150 @default.
- W3005803670 cites W2591523563 @default.
- W3005803670 cites W2604800449 @default.
- W3005803670 cites W2608279822 @default.
- W3005803670 cites W2736722474 @default.
- W3005803670 cites W2756128373 @default.
- W3005803670 cites W2766336411 @default.
- W3005803670 cites W2786142683 @default.
- W3005803670 cites W2800830250 @default.
- W3005803670 cites W2887684925 @default.
- W3005803670 cites W2887860290 @default.
- W3005803670 cites W2888563532 @default.
- W3005803670 cites W2897004509 @default.
- W3005803670 cites W2911623316 @default.
- W3005803670 cites W2936579714 @default.
- W3005803670 cites W2940741809 @default.
- W3005803670 cites W2945185267 @default.
- W3005803670 cites W2949779263 @default.
- W3005803670 cites W2952508355 @default.
- W3005803670 cites W2955542922 @default.
- W3005803670 cites W2989347084 @default.
- W3005803670 cites W2995419146 @default.
- W3005803670 cites W4236835692 @default.
- W3005803670 doi "https://doi.org/10.1021/acs.orglett.0c00412" @default.
- W3005803670 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32052974" @default.
- W3005803670 hasPublicationYear "2020" @default.
- W3005803670 type Work @default.
- W3005803670 sameAs 3005803670 @default.
- W3005803670 citedByCount "29" @default.
- W3005803670 countsByYear W30058036702020 @default.
- W3005803670 countsByYear W30058036702021 @default.
- W3005803670 countsByYear W30058036702022 @default.
- W3005803670 countsByYear W30058036702023 @default.
- W3005803670 crossrefType "journal-article" @default.
- W3005803670 hasAuthorship W3005803670A5034500497 @default.
- W3005803670 hasAuthorship W3005803670A5037934054 @default.
- W3005803670 hasAuthorship W3005803670A5056836858 @default.
- W3005803670 hasAuthorship W3005803670A5065064293 @default.
- W3005803670 hasAuthorship W3005803670A5072135340 @default.
- W3005803670 hasConcept C134121241 @default.
- W3005803670 hasConcept C134195300 @default.
- W3005803670 hasConcept C146686406 @default.
- W3005803670 hasConcept C155647269 @default.
- W3005803670 hasConcept C161790260 @default.
- W3005803670 hasConcept C166950319 @default.
- W3005803670 hasConcept C178790620 @default.
- W3005803670 hasConcept C185592680 @default.
- W3005803670 hasConcept C191897082 @default.
- W3005803670 hasConcept C192562407 @default.
- W3005803670 hasConcept C2780513484 @default.
- W3005803670 hasConcept C32909587 @default.
- W3005803670 hasConcept C71240020 @default.
- W3005803670 hasConceptScore W3005803670C134121241 @default.
- W3005803670 hasConceptScore W3005803670C134195300 @default.
- W3005803670 hasConceptScore W3005803670C146686406 @default.
- W3005803670 hasConceptScore W3005803670C155647269 @default.
- W3005803670 hasConceptScore W3005803670C161790260 @default.
- W3005803670 hasConceptScore W3005803670C166950319 @default.
- W3005803670 hasConceptScore W3005803670C178790620 @default.
- W3005803670 hasConceptScore W3005803670C185592680 @default.
- W3005803670 hasConceptScore W3005803670C191897082 @default.
- W3005803670 hasConceptScore W3005803670C192562407 @default.
- W3005803670 hasConceptScore W3005803670C2780513484 @default.
- W3005803670 hasConceptScore W3005803670C32909587 @default.
- W3005803670 hasConceptScore W3005803670C71240020 @default.
- W3005803670 hasFunder F4320337393 @default.
- W3005803670 hasIssue "5" @default.