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- W3005804649 abstract "Abstract Novel tetrakis-[2-(dibenzylamino)ethoxyl] substituted nickel (II), cobalt (II) and manganese (II) phthalocyanines were synthesized by using 4-(2-(dibenzylamino)ethoxy)phthalonitrile with corresponding metal salts in 2-N, N-dimethylaminoethanol. New phthalonitrile ligand was prepared from 2-(dibenzylamino)ethan-1-ol and 4-nitrophthalonitrile in acetonitrile at reflux temperature using potassium carbonate as catalyst. The compounds was characterized by elemental analysis, infrared, ultraviolet–visible and matrix-assisted laser desorption/ionization time-of-flight mass spectroscopic methods. Density functional theory calculations were performed for structural and electronic properties. Direct current and alternating current conductivity properties of the metallophthalocyanine films were investigated between 293−523 K and frequencies 40−100 kHz. The direct current conductivity values were calculated as 5.29 × 10−10 S/cm, 2.39 × 10-9 S/cm, and 3.04 × 10−10 S/cm, for nickel, cobalt and manganese complexes (293 K) films, respectively. Activation energies of the films were 0.50-0.70 eV for T" @default.
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- W3005804649 date "2020-05-01" @default.
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- W3005804649 title "Synthesis, characterization, DFT study, conductivity and effects of humidity on CO2 sensing properties of the novel tetrakis-[2-(dibenzylamino)ethoxyl] substituted metallophthalocyanines" @default.
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- W3005804649 doi "https://doi.org/10.1016/j.snb.2020.127860" @default.
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