Matches in SemOpenAlex for { <https://semopenalex.org/work/W3005959664> ?p ?o ?g. }
- W3005959664 endingPage "773" @default.
- W3005959664 startingPage "764" @default.
- W3005959664 abstract "Abstract We have synthesized Ag 7 nanoclusters via a facile one‐pot procedure with p‐aminothiophenol (PATP) as the ligand. The chemical component of this Ag 7 cluster is determined to be Ag 7 (C 6 H 6 NS) 7 H + by high‐resolution electrospray mass spectrometry, where a few fragment peaks are also observed such as [Ag 7 (C 6 H 6 NS) 4 H 3 Na] + . For this PATP‐protected Ag 7 cluster, we have conducted a Raman investigation to probe in the intracluster interactions and find an essentially different Raman feature from that the nascent PATP ligand, pertaining to photo‐assistant catalytic conversion of PATP to p,p'‐dimercapto azobenzene (DMAB). Utilizing density‐functional‐theory (DFT) calculations, we have performed natural population analysis, natural bond orbital analysis, and electron density difference analysis to fully demonstrate the intracluster interactions between Ag 7 clusters and the ligand. What is interesting is that the protection ligand PATP helps stabilize the Ag 7 metallic core, and in turn, the metal core Ag 7 catalyzes the protection ligands giving rise to N─N coupling reaction. On this basis, we have proposed a reaction pathway on a basis of DFT calculations to provide further insights into the reaction mechanism of PATP‐to‐DMAB conversion at the presence of the Ag 7 clusters." @default.
- W3005959664 created "2020-02-24" @default.
- W3005959664 creator A5065115274 @default.
- W3005959664 creator A5069625767 @default.
- W3005959664 creator A5072377630 @default.
- W3005959664 creator A5077475026 @default.
- W3005959664 creator A5084359302 @default.
- W3005959664 creator A5025791769 @default.
- W3005959664 date "2020-02-12" @default.
- W3005959664 modified "2023-09-29" @default.
- W3005959664 title "A Raman study on the intracluster interactions of aminothiophenol‐protected Ag 7 clusters—Photo‐assisted N─N coupling reaction of the ligand" @default.
- W3005959664 cites W1546843241 @default.
- W3005959664 cites W179471644 @default.
- W3005959664 cites W1795220504 @default.
- W3005959664 cites W1967922628 @default.
- W3005959664 cites W1973570604 @default.
- W3005959664 cites W1976181424 @default.
- W3005959664 cites W1978634069 @default.
- W3005959664 cites W1985229227 @default.
- W3005959664 cites W1988668502 @default.
- W3005959664 cites W1992650130 @default.
- W3005959664 cites W1996979900 @default.
- W3005959664 cites W1997136694 @default.
- W3005959664 cites W1998988220 @default.
- W3005959664 cites W1999577059 @default.
- W3005959664 cites W2000221411 @default.
- W3005959664 cites W2008455886 @default.
- W3005959664 cites W2012800844 @default.
- W3005959664 cites W2013623793 @default.
- W3005959664 cites W2013782123 @default.
- W3005959664 cites W2013793449 @default.
- W3005959664 cites W2017137432 @default.
- W3005959664 cites W2023036721 @default.
- W3005959664 cites W2027991752 @default.
- W3005959664 cites W2042299528 @default.
- W3005959664 cites W2043044330 @default.
- W3005959664 cites W2047887678 @default.
- W3005959664 cites W2054273170 @default.
- W3005959664 cites W2065084192 @default.
- W3005959664 cites W2066286007 @default.
- W3005959664 cites W2077866243 @default.
- W3005959664 cites W2087299740 @default.
- W3005959664 cites W2091273808 @default.
- W3005959664 cites W2094627594 @default.
- W3005959664 cites W2116346346 @default.
- W3005959664 cites W2117606081 @default.
- W3005959664 cites W2119630483 @default.
- W3005959664 cites W2123833022 @default.
- W3005959664 cites W2125027697 @default.
- W3005959664 cites W2126027968 @default.
- W3005959664 cites W2132525235 @default.
- W3005959664 cites W2132872592 @default.
- W3005959664 cites W2136950328 @default.
- W3005959664 cites W2151397004 @default.
- W3005959664 cites W2155637231 @default.
- W3005959664 cites W2269323211 @default.
- W3005959664 cites W2312345857 @default.
- W3005959664 cites W2313742852 @default.
- W3005959664 cites W2316919192 @default.
- W3005959664 cites W2317308632 @default.
- W3005959664 cites W2319679824 @default.
- W3005959664 cites W2319704708 @default.
- W3005959664 cites W2321407555 @default.
- W3005959664 cites W2324575802 @default.
- W3005959664 cites W2327998508 @default.
- W3005959664 cites W2331155731 @default.
- W3005959664 cites W2332174467 @default.
- W3005959664 cites W2333871467 @default.
- W3005959664 cites W2347043466 @default.
- W3005959664 cites W2515286324 @default.
- W3005959664 cites W2591323324 @default.
- W3005959664 cites W2623026738 @default.
- W3005959664 cites W2746642872 @default.
- W3005959664 cites W2761503646 @default.
- W3005959664 cites W2791253032 @default.
- W3005959664 cites W2885925954 @default.
- W3005959664 cites W2899153793 @default.
- W3005959664 cites W4247688682 @default.
- W3005959664 cites W633381003 @default.
- W3005959664 doi "https://doi.org/10.1002/jrs.5848" @default.
- W3005959664 hasPublicationYear "2020" @default.
- W3005959664 type Work @default.
- W3005959664 sameAs 3005959664 @default.
- W3005959664 citedByCount "0" @default.
- W3005959664 crossrefType "journal-article" @default.
- W3005959664 hasAuthorship W3005959664A5025791769 @default.
- W3005959664 hasAuthorship W3005959664A5065115274 @default.
- W3005959664 hasAuthorship W3005959664A5069625767 @default.
- W3005959664 hasAuthorship W3005959664A5072377630 @default.
- W3005959664 hasAuthorship W3005959664A5077475026 @default.
- W3005959664 hasAuthorship W3005959664A5084359302 @default.
- W3005959664 hasConcept C116569031 @default.
- W3005959664 hasConcept C120665830 @default.
- W3005959664 hasConcept C121332964 @default.
- W3005959664 hasConcept C130188946 @default.
- W3005959664 hasConcept C147597530 @default.
- W3005959664 hasConcept C152365726 @default.
- W3005959664 hasConcept C161790260 @default.