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- W3006094231 abstract "Abstract A highly enantioselective diphenylprolinol silyl ether‐mediated asymmetric Michael reaction of a variety of aldehydes and β‐substituted α‐cyano α,β‐unsaturated esters was developed. The organocatalytic conjugate addition provided synthetically useful chiral adducts possessing three consecutive stereocenters and suitably oriented functional handles that were readily transformed via a sequence of reductive‐cyclization and subsequent epimerization to furnish single isomers of 3,4,5‐trisubstituted piperidines with high levels of yield and excellent enantiopurity." @default.
- W3006094231 created "2020-02-24" @default.
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- W3006094231 date "2020-04-09" @default.
- W3006094231 modified "2023-10-15" @default.
- W3006094231 title "Asymmetric Michael Reaction of Aldehydes and α‐Cyano α,β‐Unsaturated Esters Catalyzed by Diphenylprolinol Silyl Ether; a Facile Asymmetric Route to 3,4,5‐Trisubstituted Piperidines" @default.
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- W3006094231 doi "https://doi.org/10.1002/cctc.202000113" @default.
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