FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3006276068> ?p ?o ?g. }

• W3006276068 endingPage "1111" @default.
• W3006276068 startingPage "1093" @default.
• W3006276068 abstract "Quantitative thermal analysis was carried out for tetra[methyleneoxycarbonyl(2,4,4-trimethyl)pentyl]methane. The ester has a glass transition temperature of 219 K and a melting temperature of 304 K. The heat of fusion is 51.3 kJ mol−1, and the increase in heat capacity at the glass transition is 250 J K−1 mol−1. The measured and calculated heat capacities of the solid and liquid states from 130 to 420 K are reported and a discussion of the glass and melting transitions is presented. The computation of the heat capacity made use of the Advanced Thermal Analysis System, ATHAS, using an approximate group-vibration spectrum and a Tarasov treatment of the skeletal vibrations. The experimental and calculated heat capacities of the solid ester were compared over the whole temperature range to detect changes in order and the presence of large-amplitude motion. An addition scheme for heat capacities of this and related esters was developed and used for the extrapolation of the heat capacity of the liquid state for this ester. The liquid heat capacity for the title ester is well represented by 691.1+1.668T [J K−1 mol−1]. A deficit in the entropy and enthalpy of fusion was observed relative to values estimated from empirical addition schemes, but no gradual disordering was noted outside the transition region. The final interpretation of this deficit of conformational entropy needs structure and mobility analysis by solid state13C NMR and X-ray diffraction. These analyses are reported in part II of this investigation." @default.
• W3006276068 created "2020-02-24" @default.
• W3006276068 creator A5005844659 @default.
• W3006276068 creator A5019768963 @default.
• W3006276068 creator A5024222255 @default.
• W3006276068 creator A5047469722 @default.
• W3006276068 creator A5054493865 @default.
• W3006276068 creator A5068597539 @default.
• W3006276068 date "1996-03-01" @default.
• W3006276068 modified "2023-10-14" @default.
• W3006276068 title "Analysis of a symmetric neopolyol ester" @default.
• W3006276068 cites W1837559343 @default.
• W3006276068 cites W1910157941 @default.
• W3006276068 cites W1965750852 @default.
• W3006276068 cites W1970374602 @default.
• W3006276068 cites W1970982722 @default.
• W3006276068 cites W1978672694 @default.
• W3006276068 cites W1982668954 @default.
• W3006276068 cites W1998450293 @default.
• W3006276068 cites W2000913155 @default.
• W3006276068 cites W2013246643 @default.
• W3006276068 cites W2014588470 @default.
• W3006276068 cites W2016563557 @default.
• W3006276068 cites W2019831060 @default.
• W3006276068 cites W2031648236 @default.
• W3006276068 cites W2034333008 @default.
• W3006276068 cites W2049883294 @default.
• W3006276068 cites W2057687849 @default.
• W3006276068 cites W2060345159 @default.
• W3006276068 cites W2076032281 @default.
• W3006276068 cites W2081000859 @default.
• W3006276068 cites W2087994545 @default.
• W3006276068 cites W2318568350 @default.
• W3006276068 cites W2922048961 @default.
• W3006276068 doi "https://doi.org/10.1007/bf01983623" @default.
• W3006276068 hasPublicationYear "1996" @default.
• W3006276068 type Work @default.
• W3006276068 sameAs 3006276068 @default.
• W3006276068 citedByCount "4" @default.
• W3006276068 countsByYear W30062760682017 @default.
• W3006276068 crossrefType "journal-article" @default.
• W3006276068 hasAuthorship W3006276068A5005844659 @default.
• W3006276068 hasAuthorship W3006276068A5019768963 @default.
• W3006276068 hasAuthorship W3006276068A5024222255 @default.
• W3006276068 hasAuthorship W3006276068A5047469722 @default.
• W3006276068 hasAuthorship W3006276068A5054493865 @default.
• W3006276068 hasAuthorship W3006276068A5068597539 @default.
• W3006276068 hasConcept C121332964 @default.
• W3006276068 hasConcept C122865956 @default.
• W3006276068 hasConcept C129446986 @default.
• W3006276068 hasConcept C129564387 @default.
• W3006276068 hasConcept C132459708 @default.
• W3006276068 hasConcept C134306372 @default.
• W3006276068 hasConcept C13530604 @default.
• W3006276068 hasConcept C138885662 @default.
• W3006276068 hasConcept C158525013 @default.
• W3006276068 hasConcept C159985019 @default.
• W3006276068 hasConcept C178790620 @default.
• W3006276068 hasConcept C185592680 @default.
• W3006276068 hasConcept C192562407 @default.
• W3006276068 hasConcept C204530211 @default.
• W3006276068 hasConcept C2985276288 @default.
• W3006276068 hasConcept C3288061 @default.
• W3006276068 hasConcept C33923547 @default.
• W3006276068 hasConcept C38139870 @default.
• W3006276068 hasConcept C39353612 @default.
• W3006276068 hasConcept C41895202 @default.
• W3006276068 hasConcept C521977710 @default.
• W3006276068 hasConcept C60205243 @default.
• W3006276068 hasConcept C97355855 @default.
• W3006276068 hasConceptScore W3006276068C121332964 @default.
• W3006276068 hasConceptScore W3006276068C122865956 @default.
• W3006276068 hasConceptScore W3006276068C129446986 @default.
• W3006276068 hasConceptScore W3006276068C129564387 @default.
• W3006276068 hasConceptScore W3006276068C132459708 @default.
• W3006276068 hasConceptScore W3006276068C134306372 @default.
• W3006276068 hasConceptScore W3006276068C13530604 @default.
• W3006276068 hasConceptScore W3006276068C138885662 @default.
• W3006276068 hasConceptScore W3006276068C158525013 @default.
• W3006276068 hasConceptScore W3006276068C159985019 @default.
• W3006276068 hasConceptScore W3006276068C178790620 @default.
• W3006276068 hasConceptScore W3006276068C185592680 @default.
• W3006276068 hasConceptScore W3006276068C192562407 @default.
• W3006276068 hasConceptScore W3006276068C204530211 @default.
• W3006276068 hasConceptScore W3006276068C2985276288 @default.
• W3006276068 hasConceptScore W3006276068C3288061 @default.
• W3006276068 hasConceptScore W3006276068C33923547 @default.
• W3006276068 hasConceptScore W3006276068C38139870 @default.
• W3006276068 hasConceptScore W3006276068C39353612 @default.
• W3006276068 hasConceptScore W3006276068C41895202 @default.
• W3006276068 hasConceptScore W3006276068C521977710 @default.
• W3006276068 hasConceptScore W3006276068C60205243 @default.
• W3006276068 hasConceptScore W3006276068C97355855 @default.
• W3006276068 hasIssue "3-4" @default.
• W3006276068 hasLocation W30062760681 @default.
• W3006276068 hasOpenAccess W3006276068 @default.
• W3006276068 hasPrimaryLocation W30062760681 @default.
• W3006276068 hasRelatedWork W2017470801 @default.

• next