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- W3006329199 abstract "Nonlinear shear data of an unentangled polystyrene melt [Santangelo, P. G.; J. Rheol. 2001, 45(2), 583−594] are compared to Brownian dynamics predictions of Fraenkel chains. All parameters needed to perform the comparison are obtained from the known molar mass, zero-shear viscosity, and from older data for the linear glassy contribution [Inoue, T.; Macromolecules 1991, 24(20), 5670−5675]. Comparison reveals that the magnitude of shear thinning of the unentangled melt cannot be explained unless account is taken of the flow-induced reduction of the monomeric (Kuhn segment) friction coefficient." @default.
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- W3006329199 date "2020-02-13" @default.
- W3006329199 modified "2023-09-27" @default.
- W3006329199 title "Origin of Shear Thinning in Unentangled Polystyrene Melts" @default.
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- W3006329199 doi "https://doi.org/10.1021/acs.macromol.9b02330" @default.
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