Matches in SemOpenAlex for { <https://semopenalex.org/work/W3006435316> ?p ?o ?g. }
- W3006435316 endingPage "109257" @default.
- W3006435316 startingPage "109257" @default.
- W3006435316 abstract "Abstract Studying thermal decomposition properties of the perchlorate-based molecular perovskite energetic materials is essential to facilitate the potential applications. In this work, thermal decomposition properties of potassium perchlorate (KClO4)-based molecular perovskite were investigated. Potassium perchlorate -based molecular perovskite (H2dabco)[K(ClO4)3] were prepared by the one-pot reaction of KClO4, HClO4 and triethylenediamine (dabco). The samples were characterized. The results show that (H2dabco)[K(ClO4)3] has ternary organic-inorganic perovskite crystal structures. The thermal decomposition results demonstrated that molecular perovskite (H2dabco)[K(ClO4)3] has a lower decomposition temperature (383.6 °C) and a higher heat release (2815 J g−1) than 607.7 °C and 313 J g−1 of the monocomponent KClO4, respectively. The activation energy of thermal decomposition of (H2dabco)[K(ClO4)3] had been reduced appreciably from 191.2 kJ mol−1 to 177.7 kJ mol−1. A synergistic catalysis thermal decomposition mechanism based on unique molecular perovskite structure was proposed. This work offers a novel understanding for thermal decomposition of the molecular perovskite energetic materials." @default.
- W3006435316 created "2020-02-24" @default.
- W3006435316 creator A5006960686 @default.
- W3006435316 creator A5019573704 @default.
- W3006435316 creator A5025157103 @default.
- W3006435316 creator A5048320682 @default.
- W3006435316 creator A5060412237 @default.
- W3006435316 date "2020-05-01" @default.
- W3006435316 modified "2023-10-12" @default.
- W3006435316 title "Insight into the thermal decomposition properties of potassium perchlorate (KClO4)-based molecular perovskite" @default.
- W3006435316 cites W2000320428 @default.
- W3006435316 cites W2035392202 @default.
- W3006435316 cites W2050082409 @default.
- W3006435316 cites W2313576768 @default.
- W3006435316 cites W2588981700 @default.
- W3006435316 cites W2621183751 @default.
- W3006435316 cites W2621364702 @default.
- W3006435316 cites W2768509691 @default.
- W3006435316 cites W2770657239 @default.
- W3006435316 cites W2788635844 @default.
- W3006435316 cites W2801290220 @default.
- W3006435316 cites W2896234668 @default.
- W3006435316 cites W2903081805 @default.
- W3006435316 cites W2940732777 @default.
- W3006435316 cites W2944642550 @default.
- W3006435316 cites W2945765884 @default.
- W3006435316 cites W2947994975 @default.
- W3006435316 cites W2967426644 @default.
- W3006435316 cites W2983903796 @default.
- W3006435316 cites W2995539997 @default.
- W3006435316 cites W2999605093 @default.
- W3006435316 cites W2999885909 @default.
- W3006435316 cites W3103583591 @default.
- W3006435316 doi "https://doi.org/10.1016/j.vacuum.2020.109257" @default.
- W3006435316 hasPublicationYear "2020" @default.
- W3006435316 type Work @default.
- W3006435316 sameAs 3006435316 @default.
- W3006435316 citedByCount "24" @default.
- W3006435316 countsByYear W30064353162020 @default.
- W3006435316 countsByYear W30064353162021 @default.
- W3006435316 countsByYear W30064353162022 @default.
- W3006435316 countsByYear W30064353162023 @default.
- W3006435316 crossrefType "journal-article" @default.
- W3006435316 hasAuthorship W3006435316A5006960686 @default.
- W3006435316 hasAuthorship W3006435316A5019573704 @default.
- W3006435316 hasAuthorship W3006435316A5025157103 @default.
- W3006435316 hasAuthorship W3006435316A5048320682 @default.
- W3006435316 hasAuthorship W3006435316A5060412237 @default.
- W3006435316 hasConcept C124681953 @default.
- W3006435316 hasConcept C127413603 @default.
- W3006435316 hasConcept C145148216 @default.
- W3006435316 hasConcept C155011858 @default.
- W3006435316 hasConcept C160434732 @default.
- W3006435316 hasConcept C178790620 @default.
- W3006435316 hasConcept C179104552 @default.
- W3006435316 hasConcept C185592680 @default.
- W3006435316 hasConcept C191897082 @default.
- W3006435316 hasConcept C192562407 @default.
- W3006435316 hasConcept C2776704483 @default.
- W3006435316 hasConcept C2780250386 @default.
- W3006435316 hasConcept C2780709120 @default.
- W3006435316 hasConcept C42360764 @default.
- W3006435316 hasConcept C517785266 @default.
- W3006435316 hasConcept C8010536 @default.
- W3006435316 hasConceptScore W3006435316C124681953 @default.
- W3006435316 hasConceptScore W3006435316C127413603 @default.
- W3006435316 hasConceptScore W3006435316C145148216 @default.
- W3006435316 hasConceptScore W3006435316C155011858 @default.
- W3006435316 hasConceptScore W3006435316C160434732 @default.
- W3006435316 hasConceptScore W3006435316C178790620 @default.
- W3006435316 hasConceptScore W3006435316C179104552 @default.
- W3006435316 hasConceptScore W3006435316C185592680 @default.
- W3006435316 hasConceptScore W3006435316C191897082 @default.
- W3006435316 hasConceptScore W3006435316C192562407 @default.
- W3006435316 hasConceptScore W3006435316C2776704483 @default.
- W3006435316 hasConceptScore W3006435316C2780250386 @default.
- W3006435316 hasConceptScore W3006435316C2780709120 @default.
- W3006435316 hasConceptScore W3006435316C42360764 @default.
- W3006435316 hasConceptScore W3006435316C517785266 @default.
- W3006435316 hasConceptScore W3006435316C8010536 @default.
- W3006435316 hasFunder F4320321001 @default.
- W3006435316 hasLocation W30064353161 @default.
- W3006435316 hasOpenAccess W3006435316 @default.
- W3006435316 hasPrimaryLocation W30064353161 @default.
- W3006435316 hasRelatedWork W1977409715 @default.
- W3006435316 hasRelatedWork W1997689263 @default.
- W3006435316 hasRelatedWork W2002250610 @default.
- W3006435316 hasRelatedWork W2011102572 @default.
- W3006435316 hasRelatedWork W2013201095 @default.
- W3006435316 hasRelatedWork W2026762186 @default.
- W3006435316 hasRelatedWork W2035283521 @default.
- W3006435316 hasRelatedWork W2362309743 @default.
- W3006435316 hasRelatedWork W3006435316 @default.
- W3006435316 hasRelatedWork W2170954654 @default.
- W3006435316 hasVolume "175" @default.
- W3006435316 isParatext "false" @default.
- W3006435316 isRetracted "false" @default.
- W3006435316 magId "3006435316" @default.