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- W3006571685 abstract "Two heteronuclear compounds (1 and 2) containing three ferric centers linked in facial-like mode with the magnetically silent hexacyanidocobaltate(III) anion were prepared and studied. The structural investigation revealed that both compounds are tetranuclear complexes with molecular formulas of [{Fe(L1)NC}3Co(CN)3]·2CH3OH·2.5CH3CN (1) and [{Fe(L2)NC}3Co(CN)3]·2H2O·1CH3OH (2). The magnetic properties of both complexes are controlled by the molecular design of the corresponding pentadentate Schiff base anions L12- and L22-. While compound 2 with a symmetric ligand prepared from salicylaldehyde shows high-spin state properties, compound 1 containing the asymmetric ligand with naphthalene units either is low-spin in its solvated form or shows a gradual but hysteretic spin crossover event when desolvated. The magnetic behavior was analyzed with respect to the Ising-like model and spin Hamiltonian, respectively, and the results were confronted with ab initio calculations. Additionally, the influence of structural features, lattice solvent molecules, the distribution of electronic terms, and active orbitals on the spin state properties of reported complexes is discussed." @default.
- W3006571685 created "2020-02-24" @default.
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- W3006571685 date "2020-02-11" @default.
- W3006571685 modified "2023-10-18" @default.
- W3006571685 title "Heteronuclear Iron(III)–Schiff Base Complexes with the Hexacyanidocobaltate(III) Anion: On the Quest To Understand the Governing Factors of Spin Crossover" @default.
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- W3006571685 doi "https://doi.org/10.1021/acs.inorgchem.9b03097" @default.
- W3006571685 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32045222" @default.
- W3006571685 hasPublicationYear "2020" @default.
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