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- W3007195274 abstract "Methyl 4-(1-methylpyrrolidin-2-yl)-3-oxobutanoate and hygrine are important biosynthetic intermediates for tropane alkaloids. We have developed a concise method to synthesize these two compounds from the key intermediate N-methylpyrrolinium cation. Methyl 4-(1-methylpyrrolidin-2-yl)-3-oxobutanoate and hygrine were obtained in four and six steps from commercially available 4,4-diethoxybutylamine with overall yields of 42% and 25%, respectively." @default.
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- W3007195274 date "2020-04-01" @default.
- W3007195274 modified "2023-10-13" @default.
- W3007195274 title "Concise and efficient syntheses of methyl 4-(1-methylpyrrolidin-2-yl)-3-oxobutanoate and hygrine" @default.
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- W3007195274 doi "https://doi.org/10.1139/cjc-2019-0442" @default.
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