Matches in SemOpenAlex for { <https://semopenalex.org/work/W3007209084> ?p ?o ?g. }
- W3007209084 endingPage "4353" @default.
- W3007209084 startingPage "4344" @default.
- W3007209084 abstract "An unprecedented photocatalytic system consisting of benzimidazolium aryloxide betaines (BI+–ArO–) and stoichiometric hydride reducing reagents was developed for carrying out desulfonylation reactions of N-sulfonyl-indoles, -amides, and -amines, and α-sulfonyl ketones. Measurements of absorption spectra and cyclic voltammograms as well as density functional theory (DFT) calculations were carried out to gain mechanistic information. In the catalytic system, visible-light-activated benzimidazoline aryloxides (BIH–ArO–), generated in situ by hydride reduction of the corresponding betaines BI+–ArO–, donate both an electron and a hydrogen atom to the substrates. A modified protocol was also developed so that a catalytic quantity of more easily prepared hydroxyaryl benzimidazolines (BIH–ArOH) is used along with a stoichiometric hydride donor to promote the photochemical desulfonylation reactions." @default.
- W3007209084 created "2020-03-06" @default.
- W3007209084 creator A5009551422 @default.
- W3007209084 creator A5022610075 @default.
- W3007209084 creator A5027435235 @default.
- W3007209084 creator A5032335582 @default.
- W3007209084 creator A5035556684 @default.
- W3007209084 creator A5046769478 @default.
- W3007209084 creator A5081086391 @default.
- W3007209084 creator A5083796151 @default.
- W3007209084 date "2020-02-19" @default.
- W3007209084 modified "2023-10-17" @default.
- W3007209084 title "Protocol for Visible-Light-Promoted Desulfonylation Reactions Utilizing Catalytic Benzimidazolium Aryloxide Betaines and Stoichiometric Hydride Donor Reagents" @default.
- W3007209084 cites W1863301206 @default.
- W3007209084 cites W1922458331 @default.
- W3007209084 cites W1965575064 @default.
- W3007209084 cites W1975085530 @default.
- W3007209084 cites W1976807081 @default.
- W3007209084 cites W1983520229 @default.
- W3007209084 cites W1985066293 @default.
- W3007209084 cites W1992769125 @default.
- W3007209084 cites W1996941025 @default.
- W3007209084 cites W1998350146 @default.
- W3007209084 cites W1999601844 @default.
- W3007209084 cites W2001131432 @default.
- W3007209084 cites W2012056654 @default.
- W3007209084 cites W2017685895 @default.
- W3007209084 cites W2018420324 @default.
- W3007209084 cites W2020503826 @default.
- W3007209084 cites W2031252390 @default.
- W3007209084 cites W2031493492 @default.
- W3007209084 cites W2032067237 @default.
- W3007209084 cites W2035168278 @default.
- W3007209084 cites W2048470426 @default.
- W3007209084 cites W2050379798 @default.
- W3007209084 cites W2051822378 @default.
- W3007209084 cites W2054841001 @default.
- W3007209084 cites W2057254817 @default.
- W3007209084 cites W2079380348 @default.
- W3007209084 cites W2081910612 @default.
- W3007209084 cites W2090487791 @default.
- W3007209084 cites W2093745675 @default.
- W3007209084 cites W2094398504 @default.
- W3007209084 cites W2104385653 @default.
- W3007209084 cites W2120612310 @default.
- W3007209084 cites W2136803810 @default.
- W3007209084 cites W2260627999 @default.
- W3007209084 cites W2315112119 @default.
- W3007209084 cites W2320327705 @default.
- W3007209084 cites W2320425792 @default.
- W3007209084 cites W2342772717 @default.
- W3007209084 cites W2408631314 @default.
- W3007209084 cites W2411148548 @default.
- W3007209084 cites W2418726947 @default.
- W3007209084 cites W2444070158 @default.
- W3007209084 cites W2503898252 @default.
- W3007209084 cites W2511188477 @default.
- W3007209084 cites W2546980809 @default.
- W3007209084 cites W2562295549 @default.
- W3007209084 cites W2569096509 @default.
- W3007209084 cites W2765798833 @default.
- W3007209084 cites W2769965014 @default.
- W3007209084 cites W2792976359 @default.
- W3007209084 cites W2793822271 @default.
- W3007209084 cites W2794166887 @default.
- W3007209084 cites W2884547182 @default.
- W3007209084 cites W2886097934 @default.
- W3007209084 cites W2889200244 @default.
- W3007209084 cites W2897410052 @default.
- W3007209084 cites W2923202663 @default.
- W3007209084 cites W2927469331 @default.
- W3007209084 cites W2944749859 @default.
- W3007209084 cites W2949070270 @default.
- W3007209084 cites W2949907198 @default.
- W3007209084 cites W2950444042 @default.
- W3007209084 cites W2951743042 @default.
- W3007209084 cites W2951796000 @default.
- W3007209084 cites W2962565515 @default.
- W3007209084 cites W2963566360 @default.
- W3007209084 cites W2964690560 @default.
- W3007209084 cites W777194960 @default.
- W3007209084 doi "https://doi.org/10.1021/acs.joc.0c00038" @default.
- W3007209084 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32073264" @default.
- W3007209084 hasPublicationYear "2020" @default.
- W3007209084 type Work @default.
- W3007209084 sameAs 3007209084 @default.
- W3007209084 citedByCount "18" @default.
- W3007209084 countsByYear W30072090842020 @default.
- W3007209084 countsByYear W30072090842021 @default.
- W3007209084 countsByYear W30072090842022 @default.
- W3007209084 countsByYear W30072090842023 @default.
- W3007209084 crossrefType "journal-article" @default.
- W3007209084 hasAuthorship W3007209084A5009551422 @default.
- W3007209084 hasAuthorship W3007209084A5022610075 @default.
- W3007209084 hasAuthorship W3007209084A5027435235 @default.
- W3007209084 hasAuthorship W3007209084A5032335582 @default.
- W3007209084 hasAuthorship W3007209084A5035556684 @default.
- W3007209084 hasAuthorship W3007209084A5046769478 @default.