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- W3007230151 endingPage "14350" @default.
- W3007230151 startingPage "14342" @default.
- W3007230151 abstract "We report carbonyl-stabilized phosphorus ylides as general and efficient catalysts for the cyanosilylation of ketones. The N,N-diethylacetamide derived phosphorane is identified as an extremely efficient catalyst for the cyanosilylation of dialkyl ketones, alkyl aryl ketones, diaryl ketones, and α,β-unsaturated enones with catalyst loading down to 0.005 mol %, the lowest ever known for ketone cyanosilylation. Aldehydes, aldimines, and ketimines are also viable substrates. By NMR and React IR analysis, as well as electrical conductivity experiments, it is proposed that the phosphorane acts as a Lewis base in order to mediate the reaction via the desilylative nucleophilic activation of TMSCN." @default.
- W3007230151 created "2020-03-06" @default.
- W3007230151 creator A5057829636 @default.
- W3007230151 creator A5080607495 @default.
- W3007230151 creator A5085592432 @default.
- W3007230151 date "2020-02-28" @default.
- W3007230151 modified "2023-10-06" @default.
- W3007230151 title "Carbonyl-Stabilized Phosphorus Ylide as an Organocatalyst for Cyanosilylation Reactions Using TMSCN" @default.
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- W3007230151 doi "https://doi.org/10.1021/acs.joc.9b03347" @default.
- W3007230151 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32108474" @default.
- W3007230151 hasPublicationYear "2020" @default.
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