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- W3007288252 abstract "Large silver(I) clusters stabilized by the dianionic carba‐ closo ‐dodecaboranylethynyl ligand were obtained. Crystallization of polymeric {Ag 2 (12‐C≡C‐ closo ‐1‐CB 11 H 11 )} n from dimethyl sulfoxide afforded [Ag 14 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 7 (DMSO) 12 ] · DMSO that contained an Ag I 10 cage augmented by four Ag I ions. Crystals of [Ag 16 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 8 (THF) 12 ] · 2THF were obtained from anhydrous THF and {Ag 2 (12‐C≡C‐ closo ‐1‐CB 11 H 11 )} n . In the presence of moisture the similar but water‐containing complex [Ag 16 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 8 (THF) 12 (H 2 O) 2 ] · 2.5THF was identified. Both silver(I) clusters are composed of a central octahedral Ag I 6 unit and ten further silver(I) ions bonded via argentophilic interactions. [Ag 14 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 7 (DMSO) 12 ] · DMSO and [Ag 16 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 8 (THF) 12 ] · 2THF were characterized by elemental analysis and vibrational (IR and Raman) as well as NMR spectroscopy. In addition, the crystal structures of [Ag 25 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 12 (CH 3 CN) 13.5 (OH)] · 0.5CH 3 CN and [Ag 25 (12‐C≡C‐ closo ‐1‐CB 11 H 11 ) 12 {(CH 3 ) 2 CO} 13.5 (H 2 O)Cl] · 15(CH 3 ) 2 CO were determined. Both compounds contain Ag I 14 rhombic dodecahedrons augmented by eleven silver(I) ions. A hydroxide or a chloride template ion is present in the center of the rhombic dodecahedron, respectively." @default.
- W3007288252 created "2020-03-06" @default.
- W3007288252 creator A5044847247 @default.
- W3007288252 creator A5056569207 @default.
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- W3007288252 date "2020-03-05" @default.
- W3007288252 modified "2023-10-18" @default.
- W3007288252 title "Silver(I) Clusters Stabilized by the Carba‐ <i>closo</i> ‐dodecaboranylethynyl Ligand with <i>O</i> ‐Donor Coligands and Template Ions" @default.
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- W3007288252 doi "https://doi.org/10.1002/zaac.202000009" @default.
- W3007288252 hasPublicationYear "2020" @default.
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