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- W3007340360 abstract "The selective catalytic synthesis of limonene-derived monofunctional cyclic carbonates and their subsequent functionalisation via thiol-ene addition and amine ring-opening is reported. A phosphotungstate polyoxometalate catalyst used for limonene epoxidation in the 1,2-position is shown to also be active in cyclic carbonate synthesis, allowing a two-step, one-pot synthesis without intermittent epoxide isolation. When used in conjunction with a classical halide catalyst, the polyoxometalate increased the rate of carbonation in a synergistic double-activation of both substrates. The cis isomer is shown to be responsible for incomplete conversion and by-product formation in commercial mixtures of 1,2-limomene oxide. Carbonation of 8,9-limonene epoxide furnished the 8,9-limonene carbonate for the first time. Both cyclic carbonates underwent thiol-ene addition reactions to yield linked di-monocarbonates, which can be used in linear non-isocyanate polyurethanes synthesis, as shown by their facile ring-opening with N-hexylamine. Thus, the selective catalytic route to monofunctional limonene carbonates gives straightforward access to monomers for novel bio-based polymers." @default.
- W3007340360 created "2020-03-06" @default.
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- W3007340360 date "2020-05-08" @default.
- W3007340360 modified "2023-10-17" @default.
- W3007340360 title "Selective Catalytic Synthesis of 1,2‐ and 8,9‐Cyclic Limonene Carbonates as Versatile Building Blocks for Novel Hydroxyurethanes" @default.
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- W3007340360 doi "https://doi.org/10.1002/chem.201905561" @default.
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