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- W3007376209 abstract "Three iron(III) complexes, [Fe(qnal) 2 ]Y {qnal = 1‐[(8‐quinolinylimino)methyl]‐2‐naphthalenolate; Y = NO 3 1 , BPh 4 · CH 2 Cl 2 2 , NCS 3 } have been prepared to explore anion effects in spin crossover systems. Structural studies on 2 reveal supramolecular chains formed by π–π and C–H ··· π interactions between the [Fe(qnal) 2 ] + cations. Magnetic susceptibility measurements show the onset of spin crossover in 1 above 200 K, while complete spin crossover is observed in 2 and 3 with T 1/2 = 285 and 340 K, respectively. Unusually, 2 also undergoes light‐induced excited spin state trapping (LIESST) at 980 nm with ca. 65 % efficiency and T (LIESST) = 25 K and reverse ‐LIESST at 660 nm with full reversibility over many cycles. The results highlight the important influence that the anion has on thermal and light‐activated spin crossover properties." @default.
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- W3007376209 date "2020-03-12" @default.
- W3007376209 modified "2023-10-13" @default.
- W3007376209 title "Thermal and Light‐Activated Spin Crossover in Iron(III) qnal Complexes" @default.
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- W3007376209 doi "https://doi.org/10.1002/ejic.202000115" @default.
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