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- W3007384786 abstract "The use of new photocatalysts active under visible light in cement-based building materials represents one interesting alternative to improve the air quality in the urban areas. This work undertakes the feasibility of using BiOX (X = Cl and I) as an addition on mortars for visible-light-driven NOx removal. The interaction between BiOX photocatalysts and cement matrix, and the influence of their addition on the inherent properties of the cement-based materials was studied. The NO removal by the samples ranking as follows BiOCl-cem > BiOI-cem > TiO2-cem. The higher efficiency under visible light of BiOCl-cem might be ascribed to the presence of oxygen vacancies together with a strong oxidation potential. BiOI-cem suffers a phase transformation of BiOI in alkaline media to an I-deficient bismuth oxide compound with poor visible light absorbance capability. However, BiOI-cem showed considerably higher nitrate selectivity that resulted in the highest NOx global removal efficiency. These results can make its use more environmentally sustainable than TiO2 and BiOCl cement composites." @default.
- W3007384786 created "2020-03-06" @default.
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- W3007384786 date "2020-02-14" @default.
- W3007384786 modified "2023-10-16" @default.
- W3007384786 title "Photocatalytic BiOX Mortars under Visible Light Irradiation: Compatibility, NOx Efficiency and Nitrate Selectivity" @default.
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- W3007384786 doi "https://doi.org/10.3390/catal10020226" @default.
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