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- W3007394857 abstract "The synthesis and electronic structure of a tin analogue of the cycloheptatrienyl anion are described. The reaction of 5,5-diphenyldibenzo[b,f]stannepin with lithium at low temperatures reductively cleaved a Sn–Ph bond to give a lithium salt of the stannepinyl anion, the structure of which was established by X-ray diffraction analysis. Elongating the reaction time resulted in further reduction of the other Sn–Ph bond to generate a dilithium species, the formation of which was confirmed by a trapping reaction using MeI. Unlike general cycloheptatrienyl anions, the monoanionic species was proved to be nonaromatic on the basis of the NMR and X-ray diffraction studies. When the reduction was carried out at room temperature, decomposition of the seven-membered ring followed by Z/E isomerization promoted by lithium proceeded to generate (E)-2,2′-dilithiostilbene, which forms a dimer in the crystalline state." @default.
- W3007394857 created "2020-03-06" @default.
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- W3007394857 date "2020-02-24" @default.
- W3007394857 modified "2023-10-17" @default.
- W3007394857 title "A Tin Analogue of the Cycloheptatrienyl Anion: Synthesis, Structure, and Further Reduction to Form a Dianionic Species" @default.
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- W3007394857 doi "https://doi.org/10.1021/acs.organomet.0c00042" @default.
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