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• W3007456680 abstract "Abstract The effects of various aniline stabilizers on the thermal stability of nitrocellulose (NC) were investigated via isothermal thermal decomposition dynamics. The pressure‐time curves of NC/stabilizer composites were found to have a distinct inflection point, which was not observed on the pressure‐time curves of NC. The effects of stabilizers on the isothermal thermal decomposition kinetics of NC were evaluated using Arrhenius equation and model‐fitting method, and the effect of stabilizers on the storage time of NC was estimated using Berthelot equation. Results showed that the activation energy of NC/MNA, NC/ENA, NC/ i ‐PNA, and NC/ n ‐BNA before the inflection point were 162.9, 153.3, 147.4, and 150.6 kJ mol −1 , respectively, which were significantly increased compared with that of pure NC (144.7 kJ mol −1 ). Furthermore, the time required for the decomposition extent of NC/MNA, NC/ENA, NC/ i ‐PNA, and NC/ n ‐BNA to reach 0.1 % were 24.9, 11.2, 16.7, and 11.2 years, respectively, at 298.15 K, which was longer than that required of NC (10.6 years). UV‐vis revealed that the stabilizers were almost consumed when the NC/stabilizer thermal decomposition pressure‐time curve reached the inflection point. Based on the above results, the stability order was MNA> i ‐PNA>ENA> n ‐BNA as the criterion for time of the inflection point." @default.
• W3007456680 created "2020-03-06" @default.
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• W3007456680 date "2020-02-27" @default.
• W3007456680 modified "2023-10-18" @default.
• W3007456680 title "The Effects of Aniline Stabilizers on Nitrocellulose Based on Isothermal Thermal Decomposition" @default.
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• W3007456680 doi "https://doi.org/10.1002/prep.201900390" @default.
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