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• W3007502723 abstract "Abstract anti ‐Configured 1,3‐dimethyl deoxypropionate motifs are important sub structures in natural products. Herein, we describe a bidirectional approach for the rapid construction of natural products featuring such motifs by using C 2 ‐symmetrical 1,3‐bis(boronic esters). As for its application in convergent syntheses it was important to establish a selective mono‐Zweifel olefination we describe the scope and limitations by using different 1,3‐bis(boronic esters) and nucleophiles. This protocol takes advantage of the combination of the Hoppe–Matteson–Zweifel chemistry, which was elegantly put into practice by Aggarwal et al. In order to show its applicability the total syntheses of two natural products, serricornin and (+)‐invictolide, were performed." @default.
• W3007502723 created "2020-03-06" @default.
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• W3007502723 date "2020-06-03" @default.
• W3007502723 modified "2023-10-15" @default.
• W3007502723 title "Desymmetrization of <i>C</i>₂‐Symmetric Bis(Boronic Esters) by Zweifel Olefinations" @default.
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• W3007502723 doi "https://doi.org/10.1002/chem.202000599" @default.
• W3007502723 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7384159" @default.
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