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- W3007688611 abstract "An enantioselective one-pot synthesis of 3-azabicyclo[3.1.0]hexanes from allyl carbonates and propargyl amines is reported. An amine catalyst promoted the allylic substitution to form intermediary N-allyl propargylamines, which underwent enantioselective Pd(II)/Pd(IV)-mediated oxidative cyclization in situ. The chiral ligand (P,R,R)-i-Pr-SPRIX is crucial to the cyclization, producing the desired bicyclic compounds in up to 92% yield and 90% ee." @default.
- W3007688611 created "2020-03-06" @default.
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- W3007688611 date "2020-04-08" @default.
- W3007688611 modified "2023-10-02" @default.
- W3007688611 title "Enantioselective One‐pot Synthesis of 3‐Azabicyclo[3.1.0]hexanes <i>via</i> Allylic Substitution and Oxidative Cyclization" @default.
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- W3007688611 doi "https://doi.org/10.1002/adsc.202000044" @default.
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