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• W3007784082 abstract "By applying ultrasonic cavitation, palladium particles were deposited onto the surface of two different types of carbon nanotubes (nitrogen-doped bamboo-shaped carbon nanotubes, N-BCNT and multiwalled carbon nanotubes, MWCNT). To achieve this, palladium ions have been reduced by the adsorbent (N-BCNT or MWCNT) itself. Hydroxyl functional groups were identified on the surface of the MWCNTs, while amine groups have been found on the N-BCNTs. The Zeta potential was lower (−9.8 mv) in the case of the N-BCNT sample, than for MWCNT (−6.1 mV), which was in accordance with their different dispersibility in aqueous phase. The incorporated nitrogen atoms and their oxidized forms within the N-BCNT structure lead to increased adsorption capacity and thus, this type of nanotube is more efficient adsorbent for Pd particles, than MWCNT. The higher adsorption capacity of the N-BCNTs can be explained by the presence of nitrogen atoms which increase the interaction between the Pd and nanotubes. Both Pd/nanotube systems show high catalytic activity (after 30 min – 99% aniline yield) in hydrogenation of nitrobenzene to aniline. Thus, palladium coated carbon nanotubes were synthetized in a one-step reduction procedure, and the produced composites are applicable as catalysts in heterogeneous hydrogenation reactions." @default.
• W3007784082 created "2020-03-06" @default.
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• W3007784082 date "2020-05-01" @default.
• W3007784082 modified "2023-10-01" @default.
• W3007784082 title "Ultrasonic cavitation assisted deposition of catalytically active metals on nitrogen-doped and non-doped carbon nanotubes — A comparative study" @default.
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• W3007784082 doi "https://doi.org/10.1016/j.jmrt.2020.02.054" @default.
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