Matches in SemOpenAlex for { <https://semopenalex.org/work/W3007871174> ?p ?o ?g. }
- W3007871174 endingPage "4731" @default.
- W3007871174 startingPage "4723" @default.
- W3007871174 abstract "Charge transfer and recombination across the inorganic/organic interface in nanocrystal or quantum dot (QD)-molecule hybrid materials have been extensively studied. Principles of controlling charge transfer and recombination via energetics and electronic coupling have been established. However, the use of electron spin to control transfer and recombination pathways in such systems remains relatively underexplored. Here we use CdS QD-alizarin (AZ) as a model system to demonstrate this principle. Using time-resolved spectroscopy, we found that the charge-separated states (QD--AZ+) created by selectively exciting AZ molecules mostly recombined to regenerate ground-state complexes, whereas apparently the same charge separated states created by exciting QDs recombined to produce AZ molecular triplet states. Such a difference can be traced to the distinct spin configurations between excited QDs (QD*, with an ill-defined spin) and AZ (1AZ*, spin singlet) and the asymmetric electron and hole spin-flip rates in II-VI group QDs. The transferability of such a principle was confirmed by similar observations obtained for CdS QD-tetracene complexes. Opening an avenue for controlling charge transfer and recombination pathways via electron spin is potentially important for applications such as artificial photosynthesis." @default.
- W3007871174 created "2020-03-06" @default.
- W3007871174 creator A5022960964 @default.
- W3007871174 creator A5030581701 @default.
- W3007871174 creator A5031171238 @default.
- W3007871174 creator A5033737778 @default.
- W3007871174 creator A5035322817 @default.
- W3007871174 creator A5072456195 @default.
- W3007871174 date "2020-02-18" @default.
- W3007871174 modified "2023-10-16" @default.
- W3007871174 title "Spin-Controlled Charge-Recombination Pathways across the Inorganic/Organic Interface" @default.
- W3007871174 cites W1966624508 @default.
- W3007871174 cites W1966742412 @default.
- W3007871174 cites W1989384815 @default.
- W3007871174 cites W1990796785 @default.
- W3007871174 cites W1992526463 @default.
- W3007871174 cites W2000148947 @default.
- W3007871174 cites W2008196603 @default.
- W3007871174 cites W2011880719 @default.
- W3007871174 cites W2012489083 @default.
- W3007871174 cites W2016376718 @default.
- W3007871174 cites W2021037818 @default.
- W3007871174 cites W2021203938 @default.
- W3007871174 cites W2026313128 @default.
- W3007871174 cites W2031904472 @default.
- W3007871174 cites W2032427157 @default.
- W3007871174 cites W2045573180 @default.
- W3007871174 cites W2073087976 @default.
- W3007871174 cites W2077638337 @default.
- W3007871174 cites W2093397607 @default.
- W3007871174 cites W2094070753 @default.
- W3007871174 cites W2109676747 @default.
- W3007871174 cites W2133703949 @default.
- W3007871174 cites W2142175727 @default.
- W3007871174 cites W2158848123 @default.
- W3007871174 cites W2164987951 @default.
- W3007871174 cites W2204662937 @default.
- W3007871174 cites W2304741218 @default.
- W3007871174 cites W2321447383 @default.
- W3007871174 cites W2324634416 @default.
- W3007871174 cites W2325010659 @default.
- W3007871174 cites W2325696515 @default.
- W3007871174 cites W2326153055 @default.
- W3007871174 cites W2327227278 @default.
- W3007871174 cites W2335073512 @default.
- W3007871174 cites W2466076079 @default.
- W3007871174 cites W2514089433 @default.
- W3007871174 cites W2577770616 @default.
- W3007871174 cites W2595904566 @default.
- W3007871174 cites W2605252320 @default.
- W3007871174 cites W2620540770 @default.
- W3007871174 cites W2716445482 @default.
- W3007871174 cites W2739342652 @default.
- W3007871174 cites W2761936124 @default.
- W3007871174 cites W2797577381 @default.
- W3007871174 cites W2806099578 @default.
- W3007871174 cites W2883207944 @default.
- W3007871174 cites W2887302443 @default.
- W3007871174 cites W2891198532 @default.
- W3007871174 cites W2897141836 @default.
- W3007871174 cites W2918630842 @default.
- W3007871174 cites W2918754196 @default.
- W3007871174 cites W2932585084 @default.
- W3007871174 cites W2950582982 @default.
- W3007871174 cites W2951575722 @default.
- W3007871174 cites W2967710024 @default.
- W3007871174 cites W2977919438 @default.
- W3007871174 cites W2998325888 @default.
- W3007871174 doi "https://doi.org/10.1021/jacs.9b12724" @default.
- W3007871174 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32070096" @default.
- W3007871174 hasPublicationYear "2020" @default.
- W3007871174 type Work @default.
- W3007871174 sameAs 3007871174 @default.
- W3007871174 citedByCount "25" @default.
- W3007871174 countsByYear W30078711742020 @default.
- W3007871174 countsByYear W30078711742021 @default.
- W3007871174 countsByYear W30078711742022 @default.
- W3007871174 countsByYear W30078711742023 @default.
- W3007871174 crossrefType "journal-article" @default.
- W3007871174 hasAuthorship W3007871174A5022960964 @default.
- W3007871174 hasAuthorship W3007871174A5030581701 @default.
- W3007871174 hasAuthorship W3007871174A5031171238 @default.
- W3007871174 hasAuthorship W3007871174A5033737778 @default.
- W3007871174 hasAuthorship W3007871174A5035322817 @default.
- W3007871174 hasAuthorship W3007871174A5072456195 @default.
- W3007871174 hasConcept C104317684 @default.
- W3007871174 hasConcept C121332964 @default.
- W3007871174 hasConcept C123669783 @default.
- W3007871174 hasConcept C124657808 @default.
- W3007871174 hasConcept C147120987 @default.
- W3007871174 hasConcept C156695909 @default.
- W3007871174 hasConcept C159467904 @default.
- W3007871174 hasConcept C171250308 @default.
- W3007871174 hasConcept C178790620 @default.
- W3007871174 hasConcept C179104552 @default.
- W3007871174 hasConcept C181500209 @default.
- W3007871174 hasConcept C184779094 @default.
- W3007871174 hasConcept C185592680 @default.