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- W3008086026 abstract "Abstract The reaction of diphenyl(2-pyrimidyl)phosphine (L) derived complex [Pt(L)2Cl2] with AgNO3 (1:3 M ratio, respectively) results in assembly of heterobimetallic complex [AgPt(L)2(NO3)3], wherein Pt → Ag dative bond of 2.9088(2) A is formed. This complex features thermochromic photoluminescence that appears as ~40 nm red-shift of an emission maximum upon cooling from 300 to 77 K. The related PdII/AgI complex, [AgPd(L)2(NO3)3], showing Pd → Ag dative bond of 2.9098(5) A, has also been synthesized and structurally attested." @default.
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- W3008086026 date "2020-05-01" @default.
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- W3008086026 title "Heterobimetallic PtII–AgI complex supported by diphenyl(2-pyrimidyl)phosphine: Synthesis and thermochromic photoluminescence" @default.
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