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- W3008307394 abstract "Abstract A series of bifunctional [Hpy]2[Ln2(NO3)2(ampy)4(H2shi)2] ({Ln2}; Ln = Eu(1), Gd(2) and Dy(3); H3shi = salicylhydroxamic acid; Hampy = 5-aminopyridine-2-carboxylic acid) have been synthesized and characterized. Single-crystal X-ray diffraction analyses reveal that complexes 1 and 3 are isostructural. The complexes {Ln2} exhibit either photophysical or magnetic properties in respect to the central lanthanide ion. It is rarely observed that 1 gives bright and red emission with high quantum yield (16%) and a long luminescence lifetime (547 μs). Magnetic measurement reveals that 3 exhibits significant single molecule magnet behavior with an effective energy barrier of 31 K." @default.
- W3008307394 created "2020-03-06" @default.
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- W3008307394 date "2020-04-01" @default.
- W3008307394 modified "2023-10-14" @default.
- W3008307394 title "Structural, photophysical and magnetic studies of {Ln2} assembled about oxime" @default.
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- W3008307394 doi "https://doi.org/10.1016/j.inoche.2020.107841" @default.
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