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• W3008415840 endingPage "7604" @default.
• W3008415840 startingPage "7598" @default.
• W3008415840 abstract "The enantioselective intermolecular C2-allylation of 3-substituted indoles is reported for the first time. This directing group-free approach relies on a chiral Ir-(P, olefin) complex and Mg(ClO4)2 Lewis acid catalyst system to promote allylic substitution, providing the C2-allylated products in typically high yields (40–99 %) and enantioselectivities (83–99 % ee) with excellent regiocontrol. Experimental studies and DFT calculations suggest that the reaction proceeds via direct C2-allylation, rather than C3-allylation followed by in situ migration. Steric congestion at the indole-C3 position and improved π–π stacking interactions have been identified as major contributors to the C2-selectivity." @default.
• W3008415840 created "2020-03-06" @default.
• W3008415840 creator A5000065563 @default.
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• W3008415840 creator A5023551978 @default.
• W3008415840 creator A5064536916 @default.
• W3008415840 creator A5079343295 @default.
• W3008415840 date "2020-03-11" @default.
• W3008415840 modified "2023-10-11" @default.
• W3008415840 title "Iridium‐Catalyzed Enantioselective Intermolecular Indole C2‐Allylation" @default.
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