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- W3008678586 endingPage "2110" @default.
- W3008678586 startingPage "2105" @default.
- W3008678586 abstract "An efficient method for the synthesis of tetrasubstituted furans was developed by utilizing the [1,2]-phospha-Brook rearrangement under Brønsted base catalysis. The two-step one-pot formal [3 + 2] cycloaddition involves the nucleophilic addition of a propargyl anion, which is catalytically generated through the [1,2]-phospha-Brook rearrangement, to an aldehyde and the subsequent intramolecular cyclization mediated by N-iodosuccinimide to provide 2,4,5-trisubstituted-3-iodofurans. The present method with readily available substrates provides new access to a wide range of well-organized tetrasubstituted furans." @default.
- W3008678586 created "2020-03-06" @default.
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- W3008678586 date "2020-02-25" @default.
- W3008678586 modified "2023-10-18" @default.
- W3008678586 title "Synthesis of Tetrasubstituted Furans through One-Pot Formal [3 + 2] Cycloaddition Utilizing [1,2]-Phospha-Brook Rearrangement" @default.
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- W3008678586 doi "https://doi.org/10.1021/acs.orglett.0c00619" @default.
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