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- W3008821600 abstract "Several H−H bond forming pathways have been proposed for the hydrogen evolution reaction (HER). Revealing these HER mechanisms is of fundamental importance for the rational design of catalysts and is also extremely challenging. Now, an unparalleled example of switching between homolytic and heterolytic HER mechanisms is reported. Three nickel(II) porphyrins were designed and synthesized with distinct steric effects by introducing bulky amido moieties to ortho- or para-positions of the meso-phenyl groups. These porphyrins exhibited different catalytic HER behaviors. For these Ni porphyrins, although their 1e-reduced forms are active to reduce trifluoroacetic acid, the resulting Ni hydrides (depending on the steric effects of porphyrin rings) have different pathways to make H2. Understanding HER processes, especially controllable switching between homolytic and heterolytic H−H bond formation pathways through molecular engineering, is unprecedented in electrocatalysis." @default.
- W3008821600 created "2020-03-06" @default.
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- W3008821600 date "2020-03-24" @default.
- W3008821600 modified "2023-10-11" @default.
- W3008821600 title "Homolytic versus Heterolytic Hydrogen Evolution Reaction Steered by a Steric Effect" @default.
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- W3008821600 doi "https://doi.org/10.1002/anie.202002311" @default.
- W3008821600 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32103606" @default.
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