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- W3009038555 abstract "In this article, we report the stereoselective Horner–Wadsworth–Emmons reaction of reactive carbonyl‐substituted chlorophyll a derivatives with diethyl cyanomethylphosphonate. We found that the formyl or keto group at the chlorin periphery can react stereoselectively with phosphonate carbanions to produce a series of cyanomethylene‐substituted chlorins with predominantly E geometry. Considering that no consistent records are available in the literature on the results of the allomerization of methyl pyropheophorbide a , we propose a reliable process for the transformation of this chlorophyll derivative. Our methodology represents a simple and efficient way for the preparation of novel, differently functionalized long‐wavelength absorbing chlorins, those can be applied for photodynamic therapy, solar cells, and other relevant purposes." @default.
- W3009038555 created "2020-03-13" @default.
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- W3009038555 date "2020-03-05" @default.
- W3009038555 modified "2023-10-02" @default.
- W3009038555 title "Efficient Synthesis of Long‐wavelength Absorbing Cyanochlorophyll <scp><i>a</i></scp> Derivatives via Stereoselective Horner–Wadsworth–Emmons Reaction" @default.
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- W3009038555 doi "https://doi.org/10.1002/bkcs.11998" @default.
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