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- W3009041458 endingPage "137817" @default.
- W3009041458 startingPage "137817" @default.
- W3009041458 abstract "The utilization of spent bleaching earth (SBE)-based materials for adsorption of pollutants from water and wastewater has received growing attention. In this work, a comparative study of magnetic spent bleaching earth carbon ([email protected]) and spent bleaching earth carbon ([email protected]) was performed to remove tetracycline hydrochloride (TCH) from aqueous solutions. [email protected] exhibits the larger adsorption capacity (0.238 mmol/g) obtained by the Langmuir model than the original [email protected] (0.150 mmol/g). The adsorption process fits well with the pseudo second-order model and is found to be exothermic (ΔH0 < 0) and spontaneous (ΔG0 < 0). The optimal adsorption conditions ([email protected] dose 2.217 g/L, initial TCH concentration 0.113 mmol/L, initial solution pH 6.533) predicted by the response surface methodology (RSM) are consistent with the actual verification results. The inhibition extents of coexisting cations are ranked in a decline: Al3+ > Cu2+ > Fe3+ > Mg2+ > K+ > Na+. Various characterization results indicate that the adsorption mechanism of TCH by [email protected] likely includes the π-π interactions, hydrogen bonding, electrostatic interactions, π-cations interactions, FeN covalent bonding, and changes in physical and chemical properties. [email protected] is easily solid-liquid separated using magnetic field, and can be potentially reused for 13 times before completely losing its activity, exhibiting great potential to antibiotics elimination." @default.
- W3009041458 created "2020-03-13" @default.
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- W3009041458 date "2020-06-01" @default.
- W3009041458 modified "2023-10-14" @default.
- W3009041458 title "Magnetic spent bleaching earth carbon (Mag-SBE@C) for efficient adsorption of tetracycline hydrochloride: Response surface methodology for optimization and mechanism of action" @default.
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- W3009041458 doi "https://doi.org/10.1016/j.scitotenv.2020.137817" @default.
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