FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3009096511> ?p ?o ?g. }

• W3009096511 endingPage "119574" @default.
• W3009096511 startingPage "119574" @default.
• W3009096511 abstract "The coexistence of calcium (Ca2+), sulfate (SO42−) with trace metal cations (M(II)) can possibly lead to M(II)-gypsum coprecipitation and solid solution formation. However, gypsum's role in the fixation of M(II) is still largely unknown. This study investigated the precipitation of Ca2+ and SO42− in the presence of M(II) (i.e., Cu2+, Zn2+, or Cd2+) and the incorporation of the metal cations into the gypsum structure at different environmental conditions. Trace metals in two natural gypsum samples (Yunnan and Neimeng, China) and one hydrometallurgical byproduct gypsum sample from a Cu refinery were also assessed. X-ray diffraction, scanning electron microscopy-energy dispersive X-ray spectroscopy, and Fourier transform infrared spectroscopy were employed to characterize the solid samples. The lab-scale results showed that the M(II) content in the coprecipitates increased with pH and the initial M(II) concentration. At lower pH, Zn2+ and Cd2+ were dominantly fixed through isomorphic substitution for Ca2+ in the gypsum structure, while Cu2+ was likely incorporated into the channel structure of the gypsum where the water molecules reside. In contrast, at higher pH, thermodynamic modeling results indicated that M(II)-hydroxides and base metal sulfates (Mx(OH)y(SO4)z) were formed and constituted an appreciable fraction of M(II)-bearing species in the host solids. Our study further showed that trace amounts of Cu, Zn, and Cd were also substitutianly incorporated in the two natural and one hydrometallurgical gypsum samples. The present study may have important implications for understanding the geochemical cycle of trace metals in Ca2+ and SO42− coexisting systems, as well as possible attenuation mechanisms that may occur along their supersaturation and coprecipitation." @default.
• W3009096511 created "2020-03-13" @default.
• W3009096511 creator A5029153042 @default.
• W3009096511 creator A5034137121 @default.
• W3009096511 creator A5057851239 @default.
• W3009096511 creator A5057911061 @default.
• W3009096511 creator A5061096073 @default.
• W3009096511 creator A5065149346 @default.
• W3009096511 creator A5073485469 @default.
• W3009096511 creator A5073864101 @default.
• W3009096511 creator A5075892686 @default.
• W3009096511 date "2020-05-01" @default.
• W3009096511 modified "2023-10-14" @default.
• W3009096511 title "Incorporation of trace metals Cu, Zn, and Cd into gypsum: Implication on their mobility and fate in natural and anthropogenic environments" @default.
• W3009096511 cites W1541249861 @default.
• W3009096511 cites W1966156734 @default.
• W3009096511 cites W1980977537 @default.
• W3009096511 cites W1983942792 @default.
• W3009096511 cites W1985654479 @default.
• W3009096511 cites W1996215554 @default.
• W3009096511 cites W2001359925 @default.
• W3009096511 cites W2006374819 @default.
• W3009096511 cites W2006614688 @default.
• W3009096511 cites W2011496690 @default.
• W3009096511 cites W2015190776 @default.
• W3009096511 cites W2019665383 @default.
• W3009096511 cites W2027329930 @default.
• W3009096511 cites W2034166695 @default.
• W3009096511 cites W2036087588 @default.
• W3009096511 cites W2039094878 @default.
• W3009096511 cites W2040621379 @default.
• W3009096511 cites W2041157656 @default.
• W3009096511 cites W2041754235 @default.
• W3009096511 cites W2041908200 @default.
• W3009096511 cites W2044591029 @default.
• W3009096511 cites W2050620568 @default.
• W3009096511 cites W2053068804 @default.
• W3009096511 cites W2055508627 @default.
• W3009096511 cites W2068480715 @default.
• W3009096511 cites W2075048093 @default.
• W3009096511 cites W2083904580 @default.
• W3009096511 cites W2092873416 @default.
• W3009096511 cites W2094162215 @default.
• W3009096511 cites W2102319964 @default.
• W3009096511 cites W2105184914 @default.
• W3009096511 cites W2120145199 @default.
• W3009096511 cites W2132524061 @default.
• W3009096511 cites W2167590372 @default.
• W3009096511 cites W2313235559 @default.
• W3009096511 cites W2317412243 @default.
• W3009096511 cites W2338384579 @default.
• W3009096511 cites W2473072425 @default.
• W3009096511 cites W2510930576 @default.
• W3009096511 cites W2774996699 @default.
• W3009096511 cites W2809305684 @default.
• W3009096511 cites W287498353 @default.
• W3009096511 cites W3138810719 @default.
• W3009096511 doi "https://doi.org/10.1016/j.chemgeo.2020.119574" @default.
• W3009096511 hasPublicationYear "2020" @default.
• W3009096511 type Work @default.
• W3009096511 sameAs 3009096511 @default.
• W3009096511 citedByCount "11" @default.
• W3009096511 countsByYear W30090965112020 @default.
• W3009096511 countsByYear W30090965112021 @default.
• W3009096511 countsByYear W30090965112022 @default.
• W3009096511 countsByYear W30090965112023 @default.
• W3009096511 crossrefType "journal-article" @default.
• W3009096511 hasAuthorship W3009096511A5029153042 @default.
• W3009096511 hasAuthorship W3009096511A5034137121 @default.
• W3009096511 hasAuthorship W3009096511A5057851239 @default.
• W3009096511 hasAuthorship W3009096511A5057911061 @default.
• W3009096511 hasAuthorship W3009096511A5061096073 @default.
• W3009096511 hasAuthorship W3009096511A5065149346 @default.
• W3009096511 hasAuthorship W3009096511A5073485469 @default.
• W3009096511 hasAuthorship W3009096511A5073864101 @default.
• W3009096511 hasAuthorship W3009096511A5075892686 @default.
• W3009096511 hasConcept C107054158 @default.
• W3009096511 hasConcept C121332964 @default.
• W3009096511 hasConcept C127313418 @default.
• W3009096511 hasConcept C153294291 @default.
• W3009096511 hasConcept C178790620 @default.
• W3009096511 hasConcept C179104552 @default.
• W3009096511 hasConcept C185592680 @default.
• W3009096511 hasConcept C191897082 @default.
• W3009096511 hasConcept C192562407 @default.
• W3009096511 hasConcept C199289684 @default.
• W3009096511 hasConcept C2778343803 @default.
• W3009096511 hasConcept C2778566039 @default.
• W3009096511 hasConcept C2779229104 @default.
• W3009096511 hasConcept C28737856 @default.
• W3009096511 hasConcept C535196362 @default.
• W3009096511 hasConcept C544153396 @default.
• W3009096511 hasConceptScore W3009096511C107054158 @default.
• W3009096511 hasConceptScore W3009096511C121332964 @default.
• W3009096511 hasConceptScore W3009096511C127313418 @default.
• W3009096511 hasConceptScore W3009096511C153294291 @default.
• W3009096511 hasConceptScore W3009096511C178790620 @default.
• W3009096511 hasConceptScore W3009096511C179104552 @default.

• next