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- W3009322023 endingPage "042020" @default.
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- W3009322023 abstract "Abstract In this work, a hybrid photocatalyst, PANI-CuFe 2 O 4 was synthesized, characterized and used as a photocathode for the photoelectrocatalytic (PEC) reduction of CO 2 to methanol selectively under 470 nm wavelength light irradiation at applied potential -0.4 V vs NHE. The PEC results showed that the combination of PANI with CuFe 2 O 4 could increase the rate of PEC CO 2 reduction to methanol owing to the increase of CO 2 chemisorption at the photocathode surface and at the same time by facilitating the separation of photogenerated electron-hole (e − /h + ) pairs during CO 2 reduction. The rate of methanol formation was found maximum as 49.2 μmole g −1 .h −1 with 73% Faradaic efficiency. The incident photon current efficiency (IPCE) and quantum efficiency (QE) for PEC CO 2 reduction was achieved as 7.11% and 23.9% respectively. The PEC results demonstrated that the bias potential played a significant role in the separation of e − /h + pairs and enhanced the PEC CO 2 reduction activity of the hybrid photocatalyst." @default.
- W3009322023 created "2020-03-13" @default.
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- W3009322023 date "2020-01-01" @default.
- W3009322023 modified "2023-09-26" @default.
- W3009322023 title "Selective synthesis of methanol by photoelectrocatalytic reduction of CO<sub>2</sub> over PANI-CuFe<sub>2</sub>O<sub>4</sub> hybrid catalyst" @default.
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- W3009322023 doi "https://doi.org/10.1088/1757-899x/736/4/042020" @default.
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