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- W3009471256 abstract "Scalable methods of producing functional materials is of importance. Herein, we report the use of free radical copolymerisation of ω-unsaturated methacrylic macromonomers, as derived from catalytic chain transfer polymerisation (CCTP), with acrylic monomers in solution leading to block copolymers by varying the nature of the macromonomer. We demonstrate the effect that varying the molecular weight and ester side chain length of macromonomer from CCTP, has on the polymerisation leading to either graft or diblock copolymers. DOSY NMR, MALDI-ToF/ToF MS has allowed for the exploration of the extent to which varying the concentration of macromonomer has on the products formed. Importantly, during the successful synthesis of acrylic and methacrylic diblock copolymers with broad dispersities of each block, full consumption of the macromonomers was observed." @default.
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- W3009471256 date "2019-11-13" @default.
- W3009471256 modified "2023-09-26" @default.
- W3009471256 title "Data for Methacrylate and Acrylate Diblock Copolymers via End-Capping using a combination of CCTP and FRP" @default.
- W3009471256 hasPublicationYear "2019" @default.
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