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- W3009533337 abstract "Biomaterials in nature often exhibit hierarchical chiral structures with an intriguing mechanism involving hierarchical chirality transfer from molecular to supramolecular and the nano- or microscale level. To mimic the cross-level chirality transfer, we present here one kind of host–guest complex system built of β-cyclodextrin (β-CD), sodium dodecyl sulfate (SDS), and fluorescent dyes, which show multilevel chirality, including molecular chirality of β-CD, induced supramolecular chirality of β-CD/SDS host–guest complexes, a chiral lattice self-assembled nanosheet, mesoscopic chirality of an assembled helical tube, induced chirality of a dye-doped chiral tube. The hierarchical chirality involved a chiral lattice self-assembly process, which can be identified by small-angle X-ray scattering, optical studies, circular dichroism, and circularly polarized luminescence spectral measurements. Benefiting from the chiral lattice self-assembly, intense circularly polarized luminescence was observed from the achiral dye-doped complexes with a large dissymmetry factor up to +0.1. This work thus provides a feasible insight for developing hierarchical chiroptical materials based on the lattice self-assembly." @default.
- W3009533337 created "2020-03-13" @default.
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- W3009533337 date "2020-03-04" @default.
- W3009533337 modified "2023-10-15" @default.
- W3009533337 title "Hierarchically Chiral Lattice Self-Assembly Induced Circularly Polarized Luminescence" @default.
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- W3009533337 doi "https://doi.org/10.1021/acsnano.9b08408" @default.
- W3009533337 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/32129981" @default.
- W3009533337 hasPublicationYear "2020" @default.
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