FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3009802287> ?p ?o ?g. }

• W3009802287 endingPage "1479" @default.
• W3009802287 startingPage "1473" @default.
• W3009802287 abstract "Abstract Bipyridine complexes of Ni are used as catalysts in a variety of reductive transformations. Here, the electroreduction of [Ni(Mebpy) 3 ] 2+ (Mebpy=4,4′‐dimethyl‐2,2′‐bipyridine) in dimethylformamide is reported, with the aim of determining the redox mechanism and oxidation states of products formed under well‐controlled electrochemical conditions. Results from cyclic voltammetry, steady‐state voltammetry (SSV) and chronoamperometry demonstrate that [Ni(Mebpy) 3 ] 2+ undergoes two sequential 1 e reductions at closely separated potentials ( E 1 0’ =−1.06±0.01 V and E 2 0 ’ =−1.15±0.01 V vs Ag/AgCl (3.4 M KCl)). Homogeneous comproportionation to generate [Ni(Mebpy) 3 ] + is demonstrated in SSV experiments in low ionic strength solutions. The comproportionation rate constant is determined to be >10 6 M −1 s −1 , consistent with rapid outer‐sphere electron transfer. Consequentially, on voltammetric time scales, the 2 e reduction of [Ni(Mebpy) 3 ] 2+ results in formation of [Ni(Mebpy) 3 ] + as the predominant species released into bulk solution. We also demonstrate that [Ni(Mebpy) 3 ] 0 slowly loses a Mebpy ligand (∼10 s −1 )." @default.
• W3009802287 created "2020-03-13" @default.
• W3009802287 creator A5003016148 @default.
• W3009802287 creator A5012941254 @default.
• W3009802287 creator A5022388199 @default.
• W3009802287 creator A5055043024 @default.
• W3009802287 creator A5060498869 @default.
• W3009802287 creator A5083791733 @default.
• W3009802287 creator A5089503898 @default.
• W3009802287 creator A5090975713 @default.
• W3009802287 date "2020-03-16" @default.
• W3009802287 modified "2023-09-28" @default.
• W3009802287 title "Electrochemical Reduction of [Ni(Mebpy) ₃ ] ²⁺ : Elucidation of the Redox Mechanism by Cyclic Voltammetry and Steady‐State Voltammetry in Low Ionic Strength Solutions" @default.
• W3009802287 cites W144705188 @default.
• W3009802287 cites W1966975592 @default.
• W3009802287 cites W1970738920 @default.
• W3009802287 cites W1981740333 @default.
• W3009802287 cites W1993485157 @default.
• W3009802287 cites W1998760819 @default.
• W3009802287 cites W2024537965 @default.
• W3009802287 cites W2039160357 @default.
• W3009802287 cites W2043761873 @default.
• W3009802287 cites W2051384067 @default.
• W3009802287 cites W2058547983 @default.
• W3009802287 cites W2077991980 @default.
• W3009802287 cites W2320321141 @default.
• W3009802287 cites W2734525305 @default.
• W3009802287 cites W2923189161 @default.
• W3009802287 cites W2954138255 @default.
• W3009802287 cites W350305068 @default.
• W3009802287 doi "https://doi.org/10.1002/celc.202000171" @default.
• W3009802287 hasPublicationYear "2020" @default.
• W3009802287 type Work @default.
• W3009802287 sameAs 3009802287 @default.
• W3009802287 citedByCount "10" @default.
• W3009802287 countsByYear W30098022872020 @default.
• W3009802287 countsByYear W30098022872021 @default.
• W3009802287 countsByYear W30098022872022 @default.
• W3009802287 countsByYear W30098022872023 @default.
• W3009802287 crossrefType "journal-article" @default.
• W3009802287 hasAuthorship W3009802287A5003016148 @default.
• W3009802287 hasAuthorship W3009802287A5012941254 @default.
• W3009802287 hasAuthorship W3009802287A5022388199 @default.
• W3009802287 hasAuthorship W3009802287A5055043024 @default.
• W3009802287 hasAuthorship W3009802287A5060498869 @default.
• W3009802287 hasAuthorship W3009802287A5083791733 @default.
• W3009802287 hasAuthorship W3009802287A5089503898 @default.
• W3009802287 hasAuthorship W3009802287A5090975713 @default.
• W3009802287 hasConcept C113196181 @default.
• W3009802287 hasConcept C123669783 @default.
• W3009802287 hasConcept C145148216 @default.
• W3009802287 hasConcept C147789679 @default.
• W3009802287 hasConcept C164397293 @default.
• W3009802287 hasConcept C17525397 @default.
• W3009802287 hasConcept C178790620 @default.
• W3009802287 hasConcept C179104552 @default.
• W3009802287 hasConcept C184651966 @default.
• W3009802287 hasConcept C185592680 @default.
• W3009802287 hasConcept C187428577 @default.
• W3009802287 hasConcept C2182769 @default.
• W3009802287 hasConcept C2777869211 @default.
• W3009802287 hasConcept C2778141235 @default.
• W3009802287 hasConcept C2779603750 @default.
• W3009802287 hasConcept C52859227 @default.
• W3009802287 hasConcept C55904794 @default.
• W3009802287 hasConceptScore W3009802287C113196181 @default.
• W3009802287 hasConceptScore W3009802287C123669783 @default.
• W3009802287 hasConceptScore W3009802287C145148216 @default.
• W3009802287 hasConceptScore W3009802287C147789679 @default.
• W3009802287 hasConceptScore W3009802287C164397293 @default.
• W3009802287 hasConceptScore W3009802287C17525397 @default.
• W3009802287 hasConceptScore W3009802287C178790620 @default.
• W3009802287 hasConceptScore W3009802287C179104552 @default.
• W3009802287 hasConceptScore W3009802287C184651966 @default.
• W3009802287 hasConceptScore W3009802287C185592680 @default.
• W3009802287 hasConceptScore W3009802287C187428577 @default.
• W3009802287 hasConceptScore W3009802287C2182769 @default.
• W3009802287 hasConceptScore W3009802287C2777869211 @default.
• W3009802287 hasConceptScore W3009802287C2778141235 @default.
• W3009802287 hasConceptScore W3009802287C2779603750 @default.
• W3009802287 hasConceptScore W3009802287C52859227 @default.
• W3009802287 hasConceptScore W3009802287C55904794 @default.
• W3009802287 hasFunder F4320320300 @default.
• W3009802287 hasIssue "6" @default.
• W3009802287 hasLocation W30098022871 @default.
• W3009802287 hasOpenAccess W3009802287 @default.
• W3009802287 hasPrimaryLocation W30098022871 @default.
• W3009802287 hasRelatedWork W1964179116 @default.
• W3009802287 hasRelatedWork W1986858939 @default.
• W3009802287 hasRelatedWork W2000578039 @default.
• W3009802287 hasRelatedWork W2015266738 @default.
• W3009802287 hasRelatedWork W2018621653 @default.
• W3009802287 hasRelatedWork W2074819512 @default.
• W3009802287 hasRelatedWork W2140078123 @default.
• W3009802287 hasRelatedWork W2313866617 @default.
• W3009802287 hasRelatedWork W3009802287 @default.
• W3009802287 hasRelatedWork W3137067851 @default.
• W3009802287 hasVolume "7" @default.

• next