Matches in SemOpenAlex for { <https://semopenalex.org/work/W3009946055> ?p ?o ?g. }
- W3009946055 endingPage "110863" @default.
- W3009946055 startingPage "110863" @default.
- W3009946055 abstract "The preparation of efficient and recyclable solid catalysts exhibiting high activity and selectivity toward the target product is a prerequisite to enhance the overall efficiency of a catalytic process. Herein, we study a series of Fe/Fe3C-containing nitrogen-doped porous carbon microspindles (Fe/Fe3[email protected]–x, where x stands for the pyrolysis temperature), which are core-/shell-structured hybrids, constructed by the pyrolysis of a metal–organic framework precursor as highly selective catalysts for the oxidation of sulfides to the corresponding sulfoxides under mild conditions. The Fe/Fe3[email protected]–x microspindles comprising Fe and Fe3C nanocrystals inlaid in nitrogen-doped porous carbon shells are fabricated by the direct carbonization of NH2–MIL–88B(Fe) polyhedra at 500 °C–800 °C and under nitrogen atmosphere. Among the various investigated catalysts, the Fe/Fe3[email protected]–600 microspindles exhibit the best catalytic activity, higher than those exhibited by the analogue Fe/Fe3[email protected]–600 without N doping and the commercial Fe2O3, Fe3O4, and Fe3C used for the catalytic oxidation of sulfides owing to the synergistic contribution of the Fe3C sites and adequate nitrogen doping in the porous carbon support. Furthermore, the magnetically separable properties of the Fe/Fe3[email protected]–600 microspindles enable their convenient isolation from the reaction system using an external magnet, and they can be repeatedly used for six cycles without any loss in catalytic efficiency." @default.
- W3009946055 created "2020-03-13" @default.
- W3009946055 creator A5038447744 @default.
- W3009946055 creator A5047916176 @default.
- W3009946055 creator A5053499633 @default.
- W3009946055 creator A5055897111 @default.
- W3009946055 creator A5066315160 @default.
- W3009946055 creator A5067277246 @default.
- W3009946055 creator A5067562666 @default.
- W3009946055 creator A5080202439 @default.
- W3009946055 date "2020-05-01" @default.
- W3009946055 modified "2023-10-18" @default.
- W3009946055 title "Fe/Fe3C@N-doped porous carbon microspindles templated from a metal–organic framework as highly selective and stable catalysts for the catalytic oxidation of sulfides to sulfoxides" @default.
- W3009946055 cites W1781918208 @default.
- W3009946055 cites W1883980458 @default.
- W3009946055 cites W1884575587 @default.
- W3009946055 cites W1917525767 @default.
- W3009946055 cites W1966410308 @default.
- W3009946055 cites W2002799357 @default.
- W3009946055 cites W2004550299 @default.
- W3009946055 cites W2005035420 @default.
- W3009946055 cites W2009028115 @default.
- W3009946055 cites W2014307372 @default.
- W3009946055 cites W2027541855 @default.
- W3009946055 cites W2035134417 @default.
- W3009946055 cites W2042650256 @default.
- W3009946055 cites W2083808120 @default.
- W3009946055 cites W2088420347 @default.
- W3009946055 cites W2099486431 @default.
- W3009946055 cites W2105870132 @default.
- W3009946055 cites W2141939342 @default.
- W3009946055 cites W2167405386 @default.
- W3009946055 cites W2268751425 @default.
- W3009946055 cites W2278816204 @default.
- W3009946055 cites W2296561592 @default.
- W3009946055 cites W2322306922 @default.
- W3009946055 cites W2328939392 @default.
- W3009946055 cites W2330817208 @default.
- W3009946055 cites W2416244064 @default.
- W3009946055 cites W2487153298 @default.
- W3009946055 cites W2488813449 @default.
- W3009946055 cites W2562076183 @default.
- W3009946055 cites W2568804855 @default.
- W3009946055 cites W2572949354 @default.
- W3009946055 cites W2731739699 @default.
- W3009946055 cites W2743454032 @default.
- W3009946055 cites W2746937138 @default.
- W3009946055 cites W2751132882 @default.
- W3009946055 cites W2768762172 @default.
- W3009946055 cites W2773918169 @default.
- W3009946055 cites W2792027474 @default.
- W3009946055 cites W2795838048 @default.
- W3009946055 cites W2899028077 @default.
- W3009946055 cites W2901189614 @default.
- W3009946055 cites W2902789361 @default.
- W3009946055 cites W2905933671 @default.
- W3009946055 cites W2906086722 @default.
- W3009946055 cites W2916940132 @default.
- W3009946055 cites W2943281792 @default.
- W3009946055 cites W2946562975 @default.
- W3009946055 cites W2952342204 @default.
- W3009946055 cites W2953525093 @default.
- W3009946055 cites W2953599448 @default.
- W3009946055 cites W4256555467 @default.
- W3009946055 doi "https://doi.org/10.1016/j.mcat.2020.110863" @default.
- W3009946055 hasPublicationYear "2020" @default.
- W3009946055 type Work @default.
- W3009946055 sameAs 3009946055 @default.
- W3009946055 citedByCount "10" @default.
- W3009946055 countsByYear W30099460552020 @default.
- W3009946055 countsByYear W30099460552021 @default.
- W3009946055 countsByYear W30099460552022 @default.
- W3009946055 countsByYear W30099460552023 @default.
- W3009946055 crossrefType "journal-article" @default.
- W3009946055 hasAuthorship W3009946055A5038447744 @default.
- W3009946055 hasAuthorship W3009946055A5047916176 @default.
- W3009946055 hasAuthorship W3009946055A5053499633 @default.
- W3009946055 hasAuthorship W3009946055A5055897111 @default.
- W3009946055 hasAuthorship W3009946055A5066315160 @default.
- W3009946055 hasAuthorship W3009946055A5067277246 @default.
- W3009946055 hasAuthorship W3009946055A5067562666 @default.
- W3009946055 hasAuthorship W3009946055A5080202439 @default.
- W3009946055 hasConcept C104779481 @default.
- W3009946055 hasConcept C127413603 @default.
- W3009946055 hasConcept C140205800 @default.
- W3009946055 hasConcept C150394285 @default.
- W3009946055 hasConcept C154877778 @default.
- W3009946055 hasConcept C159985019 @default.
- W3009946055 hasConcept C161790260 @default.
- W3009946055 hasConcept C178790620 @default.
- W3009946055 hasConcept C179104552 @default.
- W3009946055 hasConcept C179366358 @default.
- W3009946055 hasConcept C185592680 @default.
- W3009946055 hasConcept C191897082 @default.
- W3009946055 hasConcept C192562407 @default.
- W3009946055 hasConcept C36759035 @default.
- W3009946055 hasConcept C42360764 @default.
- W3009946055 hasConcept C537208039 @default.