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- W3010135713 abstract "Organohalogen compounds such as alkenyl bromides are versatile and essential building blocks in organic synthesis. Herein, we describe the nickel-catalyzed intermolecular carbobrominations of alkynes with aryl bromides to form highly substituted and functionalized alkenyl bromides. The reductive elimination of the carbon–bromine bond from a Ni(II) species, which is usually a disfavored process, is achieved from a high-valent Ni(III) species in this reaction. This transformation not only expands the scope of transition-metal-complex-promoted bond-forming reactions but also, more particularly, accomplishes the formation of labile bonds, which is as challenging to achieve as the cleavage of inert bonds, such as C–O or C–H bonds." @default.
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- W3010135713 date "2020-03-09" @default.
- W3010135713 modified "2023-10-13" @default.
- W3010135713 title "Nickel-Catalyzed Intermolecular Carbobromination of Alkynes" @default.
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- W3010135713 doi "https://doi.org/10.1021/acscatal.0c00980" @default.
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