FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W3010155732> ?p ?o ?g. }

• W3010155732 endingPage "381" @default.
• W3010155732 startingPage "375" @default.
• W3010155732 abstract "Abstract X-ray absorption near-edge structure (XANES) spectroscopy is a powerful technique to quantitatively investigate sulfur speciation in geologically complex materials such as minerals, glasses, soils, organic compounds, industrial slags, and extraterrestrial materials. This technique allows non-destructive investigation of the coordination chemistry and oxidation state of sulfur species ranging from sulfide (2–oxidation state) to sulfate (6+ oxidation state). Each sulfur species has a unique spectral shape with a characteristic K-edge representing the s → p and d hybridization photoelectron transitions. As such, sulfur speciation is used to measure the oxidation state of samples by comparing the overall XANES spectra to that of reference compounds. Although many S XANES spectral standards exist for terrestrial applications under oxidized conditions, new sulfide standards are needed to investigate reduced (oxygen fugacity, fO2, below IW) silicate systems relevant for studies of extraterrestrial materials and systems. Sulfides found in certain meteorites (e.g., enstatite chondrites and aubrites) and predicted to exist on Mercury, such as CaS (oldhamite), MgS (niningerite), and FeCr2S4 (daubréelite), are stable at fO2 below IW-3 but rapidly oxidize to sulfate and/or produce sulfurous gases under terrestrial surface conditions. XANES spectra of these compounds collected to date have been of variable quality, possibly due to the unstable nature of certain sulfides under typical (e.g., oxidizing) laboratory conditions. A new set of compounds was prepared for this study and their XANES spectra are analyzed for comparison with potential extraterrestrial analogs. S K-edge XANES spectra were collected at Argonne National Lab for FeS (troilite), MnS (alabandite), CaS (oldhamite), MgS (niningerite), Ni1–xS, NiS2, CaSO4 (anhydrite), MgSO4, FeSO4, Fe2(SO4)3, FeCr2S4 (daubréelite), Na2S, Al2S3, Ni7S6, and Ni3S2; the latter five were analyzed for the first time using XANES. These standards expand upon the existing S XANES end-member libraries at a higher spectral resolution (0.25 eV steps) near the S K-edge. Processed spectra, those that have been normalized and “flattened,” are compared to quantify uncertainties due to data processing methods. Future investigations that require well-characterized sulfide standards, such as the ones presented here, may have important implications for understanding sulfur speciation in reduced silicate glasses and minerals with applications for the early Earth, Moon, Mercury, and enstatite chondrites." @default.
• W3010155732 created "2020-03-13" @default.
• W3010155732 creator A5023508459 @default.
• W3010155732 creator A5031793291 @default.
• W3010155732 creator A5037837111 @default.
• W3010155732 creator A5064279954 @default.
• W3010155732 creator A5090368887 @default.
• W3010155732 date "2020-03-01" @default.
• W3010155732 modified "2023-10-03" @default.
• W3010155732 title "XANES spectroscopy of sulfides stable under reducing conditions" @default.
• W3010155732 cites W1661279915 @default.
• W3010155732 cites W1830824796 @default.
• W3010155732 cites W1972293418 @default.
• W3010155732 cites W1983434616 @default.
• W3010155732 cites W1985861081 @default.
• W3010155732 cites W1986023560 @default.
• W3010155732 cites W1993596116 @default.
• W3010155732 cites W2012950294 @default.
• W3010155732 cites W2033506740 @default.
• W3010155732 cites W2056029295 @default.
• W3010155732 cites W2069332512 @default.
• W3010155732 cites W2070227796 @default.
• W3010155732 cites W2077206475 @default.
• W3010155732 cites W2086394478 @default.
• W3010155732 cites W2090126470 @default.
• W3010155732 cites W2100903394 @default.
• W3010155732 cites W2101845176 @default.
• W3010155732 cites W2274719868 @default.
• W3010155732 cites W2292330953 @default.
• W3010155732 cites W2418385775 @default.
• W3010155732 cites W2790727788 @default.
• W3010155732 cites W2904424210 @default.
• W3010155732 cites W4247877047 @default.
• W3010155732 doi "https://doi.org/10.2138/am-2020-7146" @default.
• W3010155732 hasPublicationYear "2020" @default.
• W3010155732 type Work @default.
• W3010155732 sameAs 3010155732 @default.
• W3010155732 citedByCount "7" @default.
• W3010155732 countsByYear W30101557322020 @default.
• W3010155732 countsByYear W30101557322021 @default.
• W3010155732 countsByYear W30101557322022 @default.
• W3010155732 countsByYear W30101557322023 @default.
• W3010155732 crossrefType "journal-article" @default.
• W3010155732 hasAuthorship W3010155732A5023508459 @default.
• W3010155732 hasAuthorship W3010155732A5031793291 @default.
• W3010155732 hasAuthorship W3010155732A5037837111 @default.
• W3010155732 hasAuthorship W3010155732A5064279954 @default.
• W3010155732 hasAuthorship W3010155732A5090368887 @default.
• W3010155732 hasConcept C107872376 @default.
• W3010155732 hasConcept C110715899 @default.
• W3010155732 hasConcept C113196181 @default.
• W3010155732 hasConcept C121332964 @default.
• W3010155732 hasConcept C130635790 @default.
• W3010155732 hasConcept C178790620 @default.
• W3010155732 hasConcept C179104552 @default.
• W3010155732 hasConcept C185592680 @default.
• W3010155732 hasConcept C199289684 @default.
• W3010155732 hasConcept C2776277684 @default.
• W3010155732 hasConcept C2777335606 @default.
• W3010155732 hasConcept C2778343803 @default.
• W3010155732 hasConcept C2778591166 @default.
• W3010155732 hasConcept C2780596425 @default.
• W3010155732 hasConcept C32891209 @default.
• W3010155732 hasConcept C518881349 @default.
• W3010155732 hasConcept C540031477 @default.
• W3010155732 hasConcept C544153396 @default.
• W3010155732 hasConcept C62520636 @default.
• W3010155732 hasConcept C87355193 @default.
• W3010155732 hasConcept C93746451 @default.
• W3010155732 hasConceptScore W3010155732C107872376 @default.
• W3010155732 hasConceptScore W3010155732C110715899 @default.
• W3010155732 hasConceptScore W3010155732C113196181 @default.
• W3010155732 hasConceptScore W3010155732C121332964 @default.
• W3010155732 hasConceptScore W3010155732C130635790 @default.
• W3010155732 hasConceptScore W3010155732C178790620 @default.
• W3010155732 hasConceptScore W3010155732C179104552 @default.
• W3010155732 hasConceptScore W3010155732C185592680 @default.
• W3010155732 hasConceptScore W3010155732C199289684 @default.
• W3010155732 hasConceptScore W3010155732C2776277684 @default.
• W3010155732 hasConceptScore W3010155732C2777335606 @default.
• W3010155732 hasConceptScore W3010155732C2778343803 @default.
• W3010155732 hasConceptScore W3010155732C2778591166 @default.
• W3010155732 hasConceptScore W3010155732C2780596425 @default.
• W3010155732 hasConceptScore W3010155732C32891209 @default.
• W3010155732 hasConceptScore W3010155732C518881349 @default.
• W3010155732 hasConceptScore W3010155732C540031477 @default.
• W3010155732 hasConceptScore W3010155732C544153396 @default.
• W3010155732 hasConceptScore W3010155732C62520636 @default.
• W3010155732 hasConceptScore W3010155732C87355193 @default.
• W3010155732 hasConceptScore W3010155732C93746451 @default.
• W3010155732 hasIssue "3" @default.
• W3010155732 hasLocation W30101557321 @default.
• W3010155732 hasOpenAccess W3010155732 @default.
• W3010155732 hasPrimaryLocation W30101557321 @default.
• W3010155732 hasRelatedWork W1487906840 @default.
• W3010155732 hasRelatedWork W1971635247 @default.
• W3010155732 hasRelatedWork W1996941705 @default.
• W3010155732 hasRelatedWork W1998790027 @default.

• next