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- W3010246543 endingPage "116779" @default.
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- W3010246543 abstract "• Electrochemical extraction of Ni-Cu alloy from nickel matte has been investigated. • Nickel matte has been chlorinated and dissolved into ChCl-urea deep eutectic solvent. • Cu-Ni alloy has been successfully electrodeposited from the leached electrolyte. Direct electrochemical extraction of Cu-Ni alloy from nickel matte through chlorination and deep eutectic solvent leaching-electrodeposition processes has been investigated in this work. The reaction mechanism of the selective chlorination process and the influences of chlorination parameters including roasting temperature, roasting time and chlorinating agent addition on the chlorinated products were investigated thermodynamically and experimentally. The result shows that the sulfides (Ni 3 S 2 and Cu 2 S) contained in nickel matte can convert into chlorides (NiCl 2 and CuCl) and sulfates (Na 2 Ni(SO 4 ) 2 and NiSO 4 ) during the chlorination process. ChCl-urea deep eutectic solvent was then used to leach Cu and Ni components from the chlorinated products, and the leaching rates of Ni and Cu can reach 40.24% and 58.21%, respectively. Finally, Cu-Ni alloy has been electrodeposited from the leached electrolyte, and the morphology, phase composition, and corrosion resistance of the electrodeposited Cu-Ni alloy were systematically investigated. It is suggested that the selective chlorination and deep eutectic solvent leaching-electrodeposition processes provide a promising strategy for the extraction of Cu-Ni alloy from complex nickel matte." @default.
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- W3010246543 date "2020-07-01" @default.
- W3010246543 modified "2023-10-17" @default.
- W3010246543 title "Electrolytic production of Cu-Ni alloy from nickel matte through chlorination and deep eutectic solvent leaching-electrodeposition" @default.
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- W3010246543 doi "https://doi.org/10.1016/j.seppur.2020.116779" @default.
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