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- W3010321911 abstract "The use of gem-diborylalkenes as radical-reactive groups is explored for the first time. These reactions provide an efficient and general method for the photochemical conversion of gem-diborylalkenes to rapidly access 1,1-bisborylalkanes. This method exploits a novel photoredox decarboxylative radical addition to gem-diborylalkenes to afford α-gem-diboryl carbon-centered radicals, which benefit from additional stability by virtue of an interaction with the empty p-orbitals on borons. The reaction offers a highly modular and regioselective approach to γ-amino gem-diborylalkanes. Furthermore, EPR spectroscopy and DFT calculations have provided insight into the radical mechanism underlying the photochemistry reaction and the stability of the bis-metalated radicals, respectively." @default.
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- W3010321911 date "2020-04-15" @default.
- W3010321911 modified "2023-10-06" @default.
- W3010321911 title "Photoredox‐Mediated Reaction of <i>gem</i> ‐Diborylalkenes: Reactivity Toward Diverse 1,1‐Bisborylalkanes" @default.
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- W3010321911 doi "https://doi.org/10.1002/chem.202000603" @default.
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