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- W3010547692 abstract "Abstract The 3d‐metal mediated nitrene transfer is under intense scrutiny due to its potential as an atom economic and ecologically benign way for the directed amination of (un)functionalised C−H bonds. Here we present the isolation and characterisation of a rare, trigonal imido cobalt(III) complex, which bears a rather long cobalt–imido bond. It can cleanly cleave strong C−H bonds with a bond dissociation energy of up to 92 kcal mol −1 in an intermolecular fashion, unprecedented for imido cobalt complexes. This resulted in the amido cobalt(II) complex [Co(hmds) 2 (NH t Bu)] − . Kinetic studies on this reaction revealed an H atom transfer mechanism. Remarkably, the cobalt(II) amide itself is capable of mediating H atom abstraction or stepwise proton/electron transfer depending on the substrate. A cobalt‐mediated catalytic application for substrate dehydrogenation using an organo azide is presented." @default.
- W3010547692 created "2020-03-13" @default.
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- W3010547692 date "2020-03-27" @default.
- W3010547692 modified "2023-10-02" @default.
- W3010547692 title "C−H Bond Activation by an Imido Cobalt(III) and the Resulting Amido Cobalt(II) Complex" @default.
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- W3010547692 doi "https://doi.org/10.1002/anie.201914718" @default.
- W3010547692 hasPubMedCentralId "https://www.ncbi.nlm.nih.gov/pmc/articles/7318117" @default.
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