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- W3010690246 abstract "The phonon behavior in incipient ferroelectric (Ni 1/3 Nb 2/3 ) x Ti 1− x O 2 ceramic solid solutions is investigated with combined Raman, Fourier transformed infrared (FTIR), and dielectric spectroscopy. The (Ni+Nb) incorporation into rutile TiO 2 leads to the Raman and infrared modes broadening, the Gaussian‐type Raman peak of A 2 u (LO) mode, and the dielectric constant (at 14 K) of different compositions being proportional to the mole ratio of Ti cations. It suggests that, with increasing (Ni + Nb)‐substitution, the cationic disorder gradually develops and the disorder‐induced phonon localization occurs. In particular, the soft A 2 u mode appears to be localized to Ti‐containing regions. This work demonstrates that the combined Raman, FTIR, and dielectric analysis can effectively probe the cationic disorder and phonon localization behaviors in incipient ferroelectric (Ni 1/3 Nb 2/3 ) x Ti 1− x O 2 and provides an experimental evidence of phonon localization in 3D disordered systems with mass and spring constant disorder, which enriches the understanding of the Anderson localization in vibrational systems." @default.
- W3010690246 created "2020-03-23" @default.
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- W3010690246 date "2020-04-02" @default.
- W3010690246 modified "2023-10-16" @default.
- W3010690246 title "Disorder‐Induced Phonon Localization in Incipient Ferroelectric (Ni <sub>1/3</sub> Nb <sub>2/3</sub> ) <sub> <i>x</i> </sub> Ti <sub> 1− <i>x</i> </sub> O <sub>2</sub> Solid Solutions" @default.
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- W3010690246 doi "https://doi.org/10.1002/pssb.202000043" @default.
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