Matches in SemOpenAlex for { <https://semopenalex.org/work/W3010804967> ?p ?o ?g. }
- W3010804967 abstract "Abstract The performance of the classic Peng–Robinson (PR) and the modern Cubic-Plus-Association (CPA) equations of state were evaluated in modeling isobaric and isothermal vapor–liquid equilibria (VLE) of binary mixtures of carboxylic acids (formic, acetic, propanoic or butanoic) + water. Two functionalities of the alpha term were tested in PR, the original term proposed by Soave and the Matthias–Copeman term specially developed for modeling polar compounds. Within the Soave functionality, two generalized forms of the acentric factor were studied, the original general form and the Robinson and Peng modification for values of the acentric factor larger than 0.491. In addition, the case of PR with fitted parameters from saturated properties (as commonly obtained for modern equations of state) was also evaluated. VLE calculations without the use of a binary interaction parameter are in general more accurate with the modern CPA due to the association term; however, when a binary interaction parameter is used, the performance of the PR versions studied here are on average similar to those of CPA, and in some cases even superior. The original alpha function used in the PR equation and the original generalized form of the acentric factor are the best options for modeling organic acids + water systems when the binary interaction parameter is available. Temperature-dependent binary interaction parameters are provided as a database in modeling these complex systems." @default.
- W3010804967 created "2020-03-23" @default.
- W3010804967 creator A5027180880 @default.
- W3010804967 creator A5058319301 @default.
- W3010804967 date "2020-03-16" @default.
- W3010804967 modified "2023-09-23" @default.
- W3010804967 title "Evaluation of the Peng–Robinson and the Cubic-Plus-Association Equations of State in Modeling VLE of Carboxylic Acids with Water" @default.
- W3010804967 cites W1247512777 @default.
- W3010804967 cites W1547991840 @default.
- W3010804967 cites W1965458588 @default.
- W3010804967 cites W2021870208 @default.
- W3010804967 cites W2025747340 @default.
- W3010804967 cites W2027318250 @default.
- W3010804967 cites W2030435157 @default.
- W3010804967 cites W2048845068 @default.
- W3010804967 cites W2056140126 @default.
- W3010804967 cites W2062902153 @default.
- W3010804967 cites W2068833682 @default.
- W3010804967 cites W2068907258 @default.
- W3010804967 cites W2070033286 @default.
- W3010804967 cites W2072630244 @default.
- W3010804967 cites W2075292454 @default.
- W3010804967 cites W2078729090 @default.
- W3010804967 cites W2086131736 @default.
- W3010804967 cites W2088795707 @default.
- W3010804967 cites W2094818470 @default.
- W3010804967 cites W2102004977 @default.
- W3010804967 cites W2113277858 @default.
- W3010804967 cites W2121831664 @default.
- W3010804967 cites W2129288307 @default.
- W3010804967 cites W2138801422 @default.
- W3010804967 cites W2169447559 @default.
- W3010804967 cites W2301434781 @default.
- W3010804967 cites W2395478837 @default.
- W3010804967 cites W2401012463 @default.
- W3010804967 cites W2495447411 @default.
- W3010804967 cites W2505186267 @default.
- W3010804967 cites W2516236748 @default.
- W3010804967 cites W2517528831 @default.
- W3010804967 cites W2607879734 @default.
- W3010804967 cites W2614038160 @default.
- W3010804967 cites W2795553852 @default.
- W3010804967 cites W2905036383 @default.
- W3010804967 cites W2980456400 @default.
- W3010804967 cites W2987783971 @default.
- W3010804967 doi "https://doi.org/10.1007/s10765-020-02643-6" @default.
- W3010804967 hasPublicationYear "2020" @default.
- W3010804967 type Work @default.
- W3010804967 sameAs 3010804967 @default.
- W3010804967 citedByCount "7" @default.
- W3010804967 countsByYear W30108049672020 @default.
- W3010804967 countsByYear W30108049672021 @default.
- W3010804967 countsByYear W30108049672022 @default.
- W3010804967 crossrefType "journal-article" @default.
- W3010804967 hasAuthorship W3010804967A5027180880 @default.
- W3010804967 hasAuthorship W3010804967A5058319301 @default.
- W3010804967 hasBestOaLocation W30108049671 @default.
- W3010804967 hasConcept C121332964 @default.
- W3010804967 hasConcept C133347239 @default.
- W3010804967 hasConcept C134306372 @default.
- W3010804967 hasConcept C147789679 @default.
- W3010804967 hasConcept C163115403 @default.
- W3010804967 hasConcept C178790620 @default.
- W3010804967 hasConcept C182283691 @default.
- W3010804967 hasConcept C185592680 @default.
- W3010804967 hasConcept C192562407 @default.
- W3010804967 hasConcept C33923547 @default.
- W3010804967 hasConcept C48372109 @default.
- W3010804967 hasConcept C521977710 @default.
- W3010804967 hasConcept C53810900 @default.
- W3010804967 hasConcept C65559279 @default.
- W3010804967 hasConcept C94375191 @default.
- W3010804967 hasConcept C97355855 @default.
- W3010804967 hasConcept C98765843 @default.
- W3010804967 hasConceptScore W3010804967C121332964 @default.
- W3010804967 hasConceptScore W3010804967C133347239 @default.
- W3010804967 hasConceptScore W3010804967C134306372 @default.
- W3010804967 hasConceptScore W3010804967C147789679 @default.
- W3010804967 hasConceptScore W3010804967C163115403 @default.
- W3010804967 hasConceptScore W3010804967C178790620 @default.
- W3010804967 hasConceptScore W3010804967C182283691 @default.
- W3010804967 hasConceptScore W3010804967C185592680 @default.
- W3010804967 hasConceptScore W3010804967C192562407 @default.
- W3010804967 hasConceptScore W3010804967C33923547 @default.
- W3010804967 hasConceptScore W3010804967C48372109 @default.
- W3010804967 hasConceptScore W3010804967C521977710 @default.
- W3010804967 hasConceptScore W3010804967C53810900 @default.
- W3010804967 hasConceptScore W3010804967C65559279 @default.
- W3010804967 hasConceptScore W3010804967C94375191 @default.
- W3010804967 hasConceptScore W3010804967C97355855 @default.
- W3010804967 hasConceptScore W3010804967C98765843 @default.
- W3010804967 hasIssue "5" @default.
- W3010804967 hasLocation W30108049671 @default.
- W3010804967 hasLocation W30108049672 @default.
- W3010804967 hasLocation W30108049673 @default.
- W3010804967 hasOpenAccess W3010804967 @default.
- W3010804967 hasPrimaryLocation W30108049671 @default.
- W3010804967 hasRelatedWork W2016898163 @default.
- W3010804967 hasRelatedWork W2017928090 @default.
- W3010804967 hasRelatedWork W2035282921 @default.