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- W3010828319 abstract "Abstract Glutathione‐protected Pd, PdAu and PdPt nanoparticles (NPs) show greatly increased reactivity and stability towards the hydrogenation/isomerization of allyl alcohol in a biphasic organic/aqueous solvent mixture compared to single‐phase alkanethiol‐protected Pd‐based NPs. NPs synthesized under aerobic conditions have higher activity compared to those synthesized under nitrogen, with the highest TOF of 676 mole product/mole metal/hour for 75 : 25 PdAu NPs at 20 mL/min H 2 flow. 75 : 25 PdAu NPs prepared under nitrogen have a maximum TOF of 507 at 20 mL/min H 2 flow, but can be recycled 4 times (9 times at 8 mL/min H 2 flow). Ethyl acetate is a better organic phase solvent compared to dichloromethane and chlorobenzene in terms of TOF and recyclability. All of the NPs studied show >80 % selectivity for the isomer product (propanal). The branched, open structure of the glutathione and use of the biphasic solvent provides high catalytic activity, high selectivity, and easy removal of the products in the organic phase for good recyclability of the water‐soluble catalysts." @default.
- W3010828319 created "2020-03-23" @default.
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- W3010828319 date "2020-03-11" @default.
- W3010828319 modified "2023-09-26" @default.
- W3010828319 title "Highly Active, Selective, and Recyclable Water‐Soluble Glutathione‐Stabilized Pd and Pd‐Alloy Nanoparticle Catalysts in Biphasic Solvent" @default.
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- W3010828319 doi "https://doi.org/10.1002/cctc.201901968" @default.
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