Matches in SemOpenAlex for { <https://semopenalex.org/work/W3010981433> ?p ?o ?g. }
- W3010981433 endingPage "8848" @default.
- W3010981433 startingPage "8844" @default.
- W3010981433 abstract "N−C axially chiral compounds have emerged recently as appealing motifs for drug design. However, the enantioselective synthesis of such molecules is still poorly developed and surprisingly no metal-catalyzed atroposelective N-arylations have been described. Herein, we disclose an unprecedented Cu-catalyzed atroposelective N−C coupling that proceeds at room temperature. Such mild reaction conditions, which are a crucial parameter for atropostability of the newly generated products, are operative thanks to the use of hypervalent iodine reagents as a highly reactive coupling partners. A large panel of the N−C axially chiral compounds was afforded with very high enantioselectivity (up to >99 % ee) and good yields (up to 76 %). Post-modifications of thus accessed atropisomeric compounds allows further expansion of the diversity of these appealing compounds." @default.
- W3010981433 created "2020-03-23" @default.
- W3010981433 creator A5006905497 @default.
- W3010981433 creator A5028863682 @default.
- W3010981433 creator A5044557294 @default.
- W3010981433 creator A5057849198 @default.
- W3010981433 creator A5080368713 @default.
- W3010981433 creator A5080582820 @default.
- W3010981433 date "2020-04-06" @default.
- W3010981433 modified "2023-10-13" @default.
- W3010981433 title "Enantioselective Synthesis of N–C Axially Chiral Compounds by Cu‐Catalyzed Atroposelective Aryl Amination" @default.
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- W3010981433 doi "https://doi.org/10.1002/anie.201914876" @default.