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- W3011393127 endingPage "2821" @default.
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- W3011393127 abstract "To date, the iron-catalyzed construction of C-heteroatom bonds has been less developed due to the difficulty of transmetalation with heteroatom anions and the sluggish reductive elimination. Herein we report an iron-catalyzed method for the silylation of (hetero)aromatic chlorides. It features high efficiency, a broad substrate scope, and excellent functional group compatibility. Moreover, this protocol enables the late-stage silylation of some pharmaceuticals, thus providing an excellent method to access valuable intermediates in medicinal chemistry." @default.
- W3011393127 created "2020-03-23" @default.
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- W3011393127 date "2020-03-18" @default.
- W3011393127 modified "2023-10-12" @default.
- W3011393127 title "Iron-Catalyzed Silylation of (Hetero)aryl Chlorides with Et<sub>3</sub>SiBpin" @default.
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- W3011393127 doi "https://doi.org/10.1021/acs.orglett.0c00809" @default.
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