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• W3011522549 abstract "Radical enzymes catalyze some of the most chemically challenging CC bond-forming and bond-breaking reactions. Advances in DNA sequencing have accelerated the discovery of radical enzymes from microbes, including radical S-adenosylmethionine (rSAM) enzymes, glycyl radical enzymes (GREs), and diiron enzymes. These enzymes catalyze various reactions that yield products of industrial relevance (e.g. aromatics, hydrocarbons, and natural product derivatives), making their incorporation into engineered metabolic pathways enticing. Elucidating the mechanisms of radical enzymes that cleave and construct CC bonds will enable further enzyme discovery and engineering efforts." @default.
• W3011522549 created "2020-03-23" @default.
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• W3011522549 date "2020-10-01" @default.
• W3011522549 modified "2023-10-11" @default.
• W3011522549 title "Discovery of C C bond-forming and bond-breaking radical enzymes: enabling transformations for metabolic engineering" @default.
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• W3011522549 doi "https://doi.org/10.1016/j.copbio.2020.02.003" @default.
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